SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Rolla, M.; Franzosini, P.; Riccardi, R. L.; Bottelli, L.; Z. Naturforsch. A 22, 48-53 (1967).
Conditions:
Room Temp: 333 - 370 $\pu{K}$
Compiler:
Methodology:
The synthetic method, described by Franzosini, [1] was employed. No further details were reported.
Sample Information:
- Carlo Erba; RP; distilled through a tube filled with $\ce{P2O5}$; FP = -29.15°C.
- Fluka AG; purist grade; purification as above.
Measurement Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
Methodology Citation
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- 2,2-Dimethylbutane, $\ce{ C6H14 }$; [75-83-2] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | w1 |
|---|---|---|---|
| 59.5 | 332.7 | - | - |
| 59.5 | 332.7 | 0.915 | 88.4 |
| 77.7 | 350.9 | 0.188 | 14.1 |
| 77.7 | 350.9 | - | - |
| 85.3 | 358.5 | - | - |
| 85.3 | 358.5 | 0.829 | 77.4 |
| 86.9 | 360.1 | 0.271 | 20.8 |
| 86.9 | 360.1 | - | - |
| 93.5 | 366.7 | 0.383 | 30.5 |
| 93.5 | 366.7 | - | - |
| 94.7 | 367.9 | - | - |
| 94.7 | 367.9 | 0.733 | 66.0 |
| 95.1 | 368.3 | 0.441 | 35.8 |
| 95.1 | 368.3 | - | - |
| 95.9 | 369.1 | - | - |
| 95.9 | 369.1 | 0.697 | 62.0 |
| 96.4 | 369.6 | 0.517 | 43.1 |
| 96.4 | 369.6 | - | - |
| 96.5 | 369.7 | 0.492 | 40.7 |
| 96.5 | 369.7 | - | - |
| 96.6 | 369.8 | - | - |
| 96.6 | 369.8 | 0.619 | 53.5 |
| 96.7 | 369.9 | 0.585 | 50.0 |
| 96.7 | 369.9 | 0.585 | UCST |
