Components:
(1) Nitromethane,
CH3NO2 ; [75-52-5]
NIST WebBook
(2) Cyclohexane,
C6H12; [110-82-7]
NIST WebBook
Original Measurements
Sazonov, V. P.; Zhilyaeva, I. N.; Gudkina, L. V.; Zh. Prikl. Khim. 48, 1953-7 (1975).
Variables:
Ambient temperature: 284 - 367 K
Prepared by:
Method/Apparatus/Procedure:
The synthetic method of Alekseev 1was used. No further details were reported.
Source and Purity of Materials:
- Source not specified; pure grade reagent; distilled through a column of 15 theoretical plates; n(20°C, D) = 1.3819, d(20°C) = 1138 g L-1.
- Source not specified; pure grade reagent; distilled in a glass-packed fractionating column; n(20°C, D) = 1.4263, d(20°C) = 778.5 g L-1.
Estimated Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.
References
1 Alekseev, V. F.; Zh. Russ. Fiz. -Khim. O-va 8, 249 (1876).
Experimental Values:
Mutual solubility of nitromethane and cyclohexane
| T (°C) | T (K) | 100w1 | x1 |
|---|---|---|---|
| 11.0 | 284.15 | 1.75 | 2.40 x 10-2 |
| 11.0 | 284.15 | 96.28 | 9.727 x 10-1 |
| 50.75 | 323.9 | - | - |
| 50.75 | 323.9 | 90.01 | 9.255 x 10-1 |
| 66.85 | 340.0 | 9.99 | 1.327 x 10-1 |
| 66.85 | 340.0 | - | - |
| 76.55 | 349.7 | - | - |
| 76.55 | 349.7 | 90.01 | 8.466 x 10-1 |
| 84.25 | 357.4 | 20.01 | 2.564 x 10-1 |
| 84.25 | 357.4 | - | - |
| 87.9 | 361.05 | - | - |
| 87.9 | 361.05 | 69.98 | 7.627 x 10-1 |
| 90.45 | 363.6 | 30.05 | 3.720 x 10-1 |
| 90.45 | 363.6 | - | - |
| 91.85 | 365.0 | - | - |
| 91.85 | 365.0 | 60.04 | 6.744 x 10-1 |
| 92.15 | 365.3 | 39.0 | 4.685 x 10-1 |
| 92.15 | 365.3 | - | - |
| 93.25 | 366.4 | - | - |
| 93.25 | 366.4 | 50.01 | 5.797 x 10-1 |
| 93.65 | 366.8 | 45.02 | 5.303 x 10-1 |
| 93.65 | 366.8 | - | - |
| 93.65 | 366.8 | 47.5 | 5.55 x 10-1 |
| 93.65 | 366.8 | 47.5 | 5.55 x 10-1 |
