SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Poppe, G.; Bull. Soc. Chim. Belg. 44, 640-57 (1935).
Conditions:
Room Temp:
367
$\pu{K}$
Pressure:
329 - 12412
$\pu{kPa}$
Compiler:
Methodology:
The synthetic method was used. The observations were carried out in sealed tubes in the presence of the vapor phase. A Cailletet tube with a Kuenen electromagnetic stirrer was used in the experiments at higher pressure. A thermostating cylinder was also used to control the temperature.
Sample Information:
- Obtained from the Bureau Etalons Physico-Chimiques.
- Obtained from the Bureau Etalons Physico-Chimiques.
Measurement Errors:
Pressure: ±100 kPa
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- Cyclohexane, $\ce{ C6H12 }$; [110-82-7] NIST WebBook
Experimental Data
The upper critical solution temperature (Tc) was reported to be 93.6°C (366.8 K, compiler). A value of dTc/dP of 0.0216 K·kPa-1 was reported in the above pressure range.
