Compilation - Nitromethane with 2-Methylbutane (IUPAC SDS Volume 71)
SDS Volume (4352)
Volume 71. Nitromethane with Water or Organic Solvents, p None
Original Measurements
Rolla, M.; Franzosini, P.; Riccardi, R. L.; Bottelli, L.; Z. Naturforsch. A 22, 48-53 (1967).
Variables:
Room Temp: 351 - 369 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The synthetic method, described in detail by Franzosini, [1] was employed. No further details were reported.
Source and Purity of Materials:
- Carlo Erba; RP material; dried by passing their vapors through a tube filled with $\ce{P2O5}$; FP = -29.15°C.
- Fluka AG; puriss grade material; purification as above.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
References
Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- 2-Methylbutane, $\ce{ C5H12 }$; [78-78-4] NIST WebBook
Experimental Data
Mutual solubility of nitromethane and 2-methylbutane
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | w1 |
|---|---|---|---|
| 77.7 | 350.9 | - | - |
| 77.7 | 350.9 | 0.840 | 81.6 |
| 80.9 | 354.1 | - | - |
| 80.9 | 354.1 | 0.827 | 80.2 |
| 81.3 | 354.5 | 0.202 | 17.6 |
| 81.3 | 354.5 | - | - |
| 89.4 | 362.6 | - | - |
| 89.4 | 362.6 | 0.776 | 74.6 |
| 90.5 | 363.7 | 0.307 | 27.3 |
| 90.5 | 363.7 | - | - |
| 90.8 | 364.0 | - | - |
| 90.8 | 364.0 | 0.765 | 73.4 |
| 94.4 | 367.6 | 0.372 | 33.4 |
| 94.4 | 367.6 | - | - |
| 94.8 | 368.0 | - | - |
| 94.8 | 368.0 | 0.698 | 66.2 |
| 95.1 | 368.3 | 0.414 | 37.4 |
| 95.1 | 368.3 | - | - |
| 95.2 | 368.4 | - | - |
| 95.2 | 368.4 | 0.678 | 64.0 |
| 96.1 | 369.3 | 0.489 | 44.7 |
| 96.1 | 369.3 | 0.593 | 55.2 |
| 96.2 | 369.4 | 0.528 | 48.6 |
| 96.2 | 369.4 | 0.558 | 51.6 |
| 96.2 | 369.4 | 0.540 | 49.8 |
| 96.2 | 369.4 | 0.540 | UCST |
