Nitromethane with 1-Alkoxy-diglycerides (IUPAC SDS Volume 71)

SDS Volume

Volume 71. Nitromethane with Water or Organic Solvents, p 1336

Source Publication

Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Baumann, W. J.; Microchem. J. 11, 306-14 (1966).

Conditions:

Room Temp: 409 - 448 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

A microscope equipped with a heating stage [1] was employed for determining UCST values. No further experimental details are given.

Sample Information:
  1. Fisher Scientific Co.; certified, No. N-98.
  2. Synthesized as in Baumann and Mangold [2].
Measurement Errors:

Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.

Methodology Citations

1 Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
2 Baumann, W. J.; Mangold, H. K.; J. Org. Chem. 29, 3055 (1964).

System Components:
  1. Nitromethane $\ce{ CH3NO2 }$ [75-52-5]; NIST WebBook
  2. 1-[(Octadecyloxy)methyl]-1,2-ethanediyl ester lauric acid $\ce{ C45H88O5 }$ [10322-28-8]; NIST WebBook
    1-[(Octadecyloxy)methyl]-1,2-ethanediyl ester tetradecanoic acid $\ce{ C49H96O5 }$ [10322-29-9]; NIST WebBook
    (Z)-[(9-Octadecenyloxy)methyl]-1,2-ethanediyl ester oleic acid $\ce{ C57H106O5 }$ [10322-38-0]; NIST WebBook
    1-[(Decyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C49H96O5 }$ [10431-17-1]; NIST WebBook
    1-[(Undecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C50H98O5 }$ [10322-31-3]; NIST WebBook
    1-[(Dodecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C51H100O5 }$ [10322-32-4]; NIST WebBook
    1-[(Octadecyloxy)methyl]-1,2-ethanediyl ester oleic acid $\ce{ C57H108O5 }$ [10329-25-6]; NIST WebBook
    1-[(Tridecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C52H102O5 }$ [10322-33-5]; NIST WebBook
    1-[(Undecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C50H98O5 }$ [10322-31-3]; NIST WebBook
    1-[(Tetradecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C53H104O5 }$ [10322-34-6]; NIST WebBook
    1-[(Pentadecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C54H106O5 }$ [10431-21-7]; NIST WebBook
    (Z)-[(9-Octadecenyloxy)methyl]-ethylene ester stearic acid $\ce{ C57H110O5 }$ [10322-37-9]; NIST WebBook
    1-[(Hexadecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C55H108O5 }$ [923-63-7]; NIST WebBook
    1-[(Heptadecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C56H110O5 }$ [10322-27-7]; NIST WebBook
    1-[(Octadecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C57H112O5 }$ [923-62-6]; NIST WebBook
    1-[(Nonadecyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C58H114O5 }$ [10322-39-1]; NIST WebBook
    1-[(Eicosyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C59H116O5 }$ [10322-40-4]; NIST WebBook
    1-[(Heneicosyloxy)methyl]-1,2-ethanediyl ester stearic acid $\ce{ C60H118O5 }$ [10322-41-5]; NIST WebBook
    1-[(Octadecyloxy)methyl]-ethylene ester eicosanoic acid $\ce{ C61H120O5 }$ [10322-36-8]; NIST WebBook
Experimental Data

Upper critical solution temperatures of the systems nitromethane (1) with 1-alkoxy-diglycerides (2)

1-Alkoxy-diglycerides (x19) $T$ (°C) $T$ ($\pu{K}$)
1-[(Octadecyloxy)methyl]-1,2-ethanediyl ester lauric acid (link to XML output link to JSON output link to JSON-LD output) 135.5408.7
1-[(Octadecyloxy)methyl]-1,2-ethanediyl ester tetradecanoic acid (link to XML output link to JSON output link to JSON-LD output) 144.0417.2
(Z)-[(9-Octadecenyloxy)methyl]-1,2-ethanediyl ester oleic acid (link to XML output link to JSON output link to JSON-LD output) 146.0419.2
1-[(Decyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 146.5419.7
1-[(Undecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 149.0422.2
1-[(Dodecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 151.0424.2
1-[(Octadecyloxy)methyl]-1,2-ethanediyl ester oleic acid (link to XML output link to JSON output link to JSON-LD output) 152.0425.2
1-[(Tridecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 155.0428.2
1-[(Undecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 157.5430.7
1-[(Tetradecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 158.0431.2
1-[(Pentadecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 158.5431.7
(Z)-[(9-Octadecenyloxy)methyl]-ethylene ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 160.0433.2
1-[(Hexadecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 162.0435.2
1-[(Heptadecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 164.0437.2
1-[(Octadecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 166.5439.7
1-[(Nonadecyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 168.5441.7
1-[(Eicosyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 170.5443.7
1-[(Heneicosyloxy)methyl]-1,2-ethanediyl ester stearic acid (link to XML output link to JSON output link to JSON-LD output) 172.5445.7
1-[(Octadecyloxy)methyl]-ethylene ester eicosanoic acid (link to XML output link to JSON output link to JSON-LD output) 175.0448.2