Components:
(1) Nitromethane,
CH3NO2 ; [75-52-5]
NIST WebBook
(2) 1-Alkoxy-diglycerides,
C45H88O5 - C61H120O5; [class-005]
NIST WebBook
Original Measurements
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Baumann, W. J.; Microchem. J. 11, 306-14 (1966).
Variables:
Ambient temperature: 409 - 448 K
Prepared by:
Method/Apparatus/Procedure:
A microscope equipped with a heating stage1 was employed for determining UCST values. No further experimental details are given.
Source and Purity of Materials:
- Fisher Scientific Co.; certified, No. N-98.
- Synthesized as in Baumann and Mangold.2.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
References
1
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
2
Baumann, W. J.; Mangold, H. K.; J. Org. Chem. 29, 3055 (1964).
Experimental Values:
Upper critical solution temperatures of the systems nitromethane + 1-alkoxy-diglyceride
| T (°C) | T (K) |
|---|---|
| 135.5 | 408.7 |
| 144.0 | 417.2 |
| 146.0 | 419.2 |
| 146.5 | 419.7 |
| 149.0 | 422.2 |
| 151.0 | 424.2 |
| 152.0 | 425.2 |
| 155.0 | 428.2 |
| 157.5 | 430.7 |
| 158.0 | 431.2 |
| 158.5 | 431.7 |
| 160.0 | 433.2 |
| 162.0 | 435.2 |
| 164.0 | 437.2 |
| 166.5 | 439.7 |
| 168.5 | 441.7 |
| 170.5 | 443.7 |
| 172.5 | 445.7 |
| 175.0 | 448.2 |
