SDS Volume
Volume 37. Hydrocarbons in Water and Seawater, Part I, p 364
Source Publication
Tsonopoulos, C.; Wilson, G. M.; AIChE J. 1983, 29, 990-9.
Conditions:
Room Temp:
311 - 473
$\pu{K}$
Pressure:
0.05 - 3.5
$\pu{MPa}$
Compiler:
Methodology:
All experimental details are given in an Appendix deposited in a Documentation Centre rather than in the original paper. The solubility of (1) in (2) was measured by gas chromatography, whilst that of (2) in (1) was measured by Karl Fischer titration.
Sample Information:
- Not details given.
- no details given.
Measurement Errors:
Ambient temperature: not stated.
Mass concentration (m/v) (1): ±5% relative; repeatability of replicate anlyses.
Pressure: ±1%; type of error not stated.
System Components:
- Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
The three phase critical point was reported to be 496.7 K, 5.295 Mpa and x1 = 4.982 (0.239 g(1)/100 g sln, compiler).
The authors also report equations fitted to their own and literature data over the range 273-497 K, viz.
ln x1 = -367.9847 + 16128.646/T + 52.820813 ln T
ln x2 = -45.1714 - 1635.73/T + 7.53503 ln T
| $T$ ($\pu{K}$) | $P$ ($\pu{MPa}$) | $x_{1}$ | MR1 (g1/100 g sln) |
|---|---|---|---|
| 310.93 | - | 2.38 x 10-5 | 0.114 |
| 366.48 | - | 5.73 x 10-5 | 0.274 |
| 367.55 | - | 5.35 x 10-5 | 0.256 |
| 373.15 | 0.3482 | 6.21 x 10-5 | 0.297 |
| 422.04 | - | 2.71 x 10-4 | 0.0130 |
| 423.15 | 1.2548 | 3.39 x 10-4 | 0.0162 |
| 473.15 | 3.516 | 1.85 x 10-3 | 0.0885 |
(a) Not specified.
(b) Average value.
