SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p 1317
Source Publication
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 11, 376-83 (1966).
Conditions:
Room Temp: 343 and 360 $\pu{K}$
Compiler:
Methodology:
The synthetic method was used. As described in Schmid, et al. [1], a microscope equipped with a heating stage was used. The sealed glass capillary, containing (1) and (2), was held on the heating stage by an aluminum slide. The stage was cooled by acetone/$\ce{CO2}$, and heated electrically by a regulating transformer. For capillaries with inner diameter 0.2 to 0.3 mm, the amount required for one CST determination is about 0.2 to 2 μL.
Sample Information:
- Fisher Scientific Co.
- Not specified.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.
Methodology Citation
1 Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
System Components:
- Nitromethane $\ce{ CH3NO2 }$ [75-52-5]; NIST WebBook
-
12-Hydroxy-cis-9-octadecenoic acid $\ce{ C18H34O3 }$
[141-22-0];
NIST WebBook
12-Hydroxyoctadecanoic acid $\ce{ C18H36O3 }$ [106-14-9]; NIST WebBook
Experimental Data
Upper critical solution temperatures of the systems nitromethane (1) with hydroxy acids (2)
| Hydroxy acids (x2) | $T$ (°C) | $T$ ($\pu{K}$) |
|---|---|---|
12-Hydroxy-cis-9-octadecenoic acid
(
 )
|
70.0 | 343.2 |
|
12-Hydroxyoctadecanoic acid
(
)
|
86.5 | 359.7 |