Components:
(1) Nitromethane,
CH3NO2 ; [75-52-5]
NIST WebBook
(2) 1,2-Dialkyl glyceryl ethers,
C33H68O3 - C41H84O3; [class-077]
NIST WebBook
Original Measurements
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Baumann, W. J.; Microchem. J. 11, 306-14 (1966).
Variables:
Ambient temperature: 396 - 427 K
Prepared by:
Method/Apparatus/Procedure:
A microscope equipped with a heating stage1 was employed for determining UCST values. No further experimental details are given.
Source and Purity of Materials:
- Fisher Scientific Co.; certified, No. N-98.
- Synthesized as in Baumann and Mangold.2
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
References
1
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
2
Baumann, W. J.; Mangold, H. K.; J. Org. Chem. 29, 3055 (1964).
Experimental Values:
Upper critical solution temperatures of the systems nitromethane + 1,2-dialkyl glyceryl ether
| T (°C) | T (K) |
|---|---|
| 123.0 | 396.2 |
| 126.0 | 399.2 |
| 131.5 | 404.7 |
| 132.0 | 405.2 |
| 136.0 | 409.2 |
| 136.5 | 409.7 |
| 136.5 | 409.7 |
| 139.5 | 412.7 |
| 139.5 | 412.7 |
| 147.0 | 420.2 |
| 154.0 | 427.2 |


