SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p 1301
Source Publication
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Baumann, W. J.; Microchem. J. 11, 306-14 (1966).
Conditions:
Room Temp: 396 - 427 $\pu{K}$
Compiler:
Methodology:
A microscope equipped with a heating stage [1] was employed for determining UCST values. No further experimental details are given.
Sample Information:
- Fisher Scientific Co.; certified, No. N-98.
- Synthesized as in Baumann and Mangold [2].
Measurement Errors:
Upper Critical Solution Temperature: Not specified.
Methodology Citations
1
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
2
Baumann, W. J.; Mangold, H. K.; J. Org. Chem. 29, 3055 (1964).
System Components:
- Nitromethane $\ce{ CH3NO2 }$ [75-52-5]; NIST WebBook
-
2-(Dodecyloxy)-3-(octadecyloxy)-1-propanol $\ce{ C33H68O3 }$
[6076-36-4];
NIST WebBook
2,3-bis[(Z)-octadec-9-enoxy]propan-1-ol $\ce{ C39H76O3 }$ [6076-41-1]; NIST WebBook
3-(Octadecyloxy)-2-(tetradecyloxy)-1-propanol $\ce{ C35H72O3 }$ [6076-37-5]; NIST WebBook
2,3-Bis(hexadecyloxy)-1-propanol $\ce{ C35H72O3 }$ [6076-35-3]; NIST WebBook
3-(Octadecyloxy)-2-(cis-9-octadecenyloxy)-1-propanol $\ce{ C39H78O3 }$
3-(cis-9-Octadecenyloxy)-2-(octadecyloxy)-1-propanol $\ce{ C39H78O3 }$
3-(Octadecyloxy)-2-(trans-9-octadecenyloxy)-1-propanol $\ce{ C39H78O3 }$
3-(Hexadecyloxy)-2-(octadecyloxy)-1-propanol $\ce{ C37H76O3 }$ [6110-57-2]; NIST WebBook
2-(Hexadecyloxy)-3-(octadecyloxy)-1-propanol $\ce{ C37H76O3 }$ [6110-58-3]; NIST WebBook
2,3-Bis(octadecyloxy)-1-propanol $\ce{ C39H80O3 }$ [6076-38-6]; NIST WebBook
2-(Eicosyloxy)-3-(octadecyloxy)-1-propanol $\ce{ C41H84O3 }$ [6068-26-4]; NIST WebBook
Experimental Data
Upper critical solution temperatures of the systems nitromethane (1) with 1,2-dialkyl glyceryl ethers (2)
| 1,2-Dialkyl glyceryl ethers | $t$ (°C) | $t$ ($\pu{K}$) |
|---|---|---|
2-(Dodecyloxy)-3-(octadecyloxy)-1-propanol
(
 )
|
123.0 | 396.2 |
|
2,3-bis[(Z)-octadec-9-enoxy]propan-1-ol
(
)
|
126.0 | 399.2 |
|
3-(Octadecyloxy)-2-(tetradecyloxy)-1-propanol
(
)
|
131.5 | 404.7 |
|
2,3-Bis(hexadecyloxy)-1-propanol
(
)
|
132.0 | 405.2 |
|
3-(Octadecyloxy)-2-(cis-9-octadecenyloxy)-1-propanol
(
)
|
136.0 | 409.2 |
|
3-(cis-9-Octadecenyloxy)-2-(octadecyloxy)-1-propanol
(
)
|
136.5 | 409.7 |
|
3-(Octadecyloxy)-2-(trans-9-octadecenyloxy)-1-propanol
(
)
|
136.5 | 409.7 |
|
3-(Hexadecyloxy)-2-(octadecyloxy)-1-propanol
(
)
|
139.5 | 412.7 |
|
2-(Hexadecyloxy)-3-(octadecyloxy)-1-propanol
(
)
|
139.5 | 412.7 |
|
2,3-Bis(octadecyloxy)-1-propanol
(
)
|
147.0 | 420.2 |
|
2-(Eicosyloxy)-3-(octadecyloxy)-1-propanol
(
)
|
154.0 | 427.2 |