Compilation - Nitromethane with 1-Alkyl glyceryl ethers (IUPAC SDS Volume 71)

SDS Volume (4270)

Volume 71. Nitromethane with Water or Organic Solvents, p 1301

Original Measurements

Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Baumann, W. J.; Microchem. J. 11, 306-14 (1966).

Variables:

Room Temp: 326 - 369 $\pu{K}$

Prepared by:

V.P. Sazonov

Method/Apparatus/Procedure:

A microscope equipped with a heating stage [1] was employed for determining UCST values. No further experimental details are given.

Source and Purity of Materials:
  1. Fisher Scientific Co.; certified, No. N-98.
  2. Synthesized as in Baumann and Mangold [2].
Estimated Errors:

Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.

References

1 Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
2 Baumann, W. J.; Mangold, H. K.; J. Org. Chem. 29, 3055 (1964).

Components:
  1. Nitromethane $\ce{ CH3NO2 }$ [75-52-5]; NIST WebBook
  2. 1-(cis,cis,cis-9,12,15-octadecatrienoxy)-2,3-propanediol $\ce{ C21H38O3 }$
    1-decoxy-2,3-propanediol $\ce{ C13H28O3 }$ [92219-12-0]; NIST WebBook
    1-Undecoxy-2,3-propanediol $\ce{ C13H28O3 }$ [126923-57-7]; NIST WebBook
    1-(cis,cis-9,12-octadecadienoxy)-2,3-propanediol $\ce{ C21H40O3 }$ [70518-62-6]; NIST WebBook
    1-dodecoxy-2,3-propanediol $\ce{ C15H32O3 }$ [1561-07-5]; NIST WebBook
    1-(cis-9-hexadecenoxy)-2,3-propanediol $\ce{ C19H38O3 }$
    1-Tridecoxy-2,3-propanediol $\ce{ C16H34O3 }$ [126923-58-8]; NIST WebBook
    1-Tetradecoxy-2,3-propanediol $\ce{ C17H36O3 }$ [92219-13-1]; NIST WebBook
    1-(cis-9-octadecenoxy)-2,3-propanediol $\ce{ C21H42O3 }$ [2929-07-9]; NIST WebBook
    1-(trans-9-octadecenoxy)-2,3-propanediol $\ce{ C21H42O3 }$ [593-31-7]; NIST WebBook
    1-pentadecoxy-2,3-propanediol $\ce{ C18H38O3 }$ [124770-96-3]; NIST WebBook
    1-hexadecoxy-2,3-propanediol $\ce{ C19H40O3 }$ [506-03-6]; NIST WebBook
    1-heptadecoxy-2,3-propanediol $\ce{ C20H42O3 }$ [113817-63-3]; NIST WebBook
    1-octadecoxy-2,3-propanediol $\ce{ C21H44O3 }$ [544-62-7]; NIST WebBook
    1-nonadecoxy-2,3-propanediol $\ce{ C22H46O3 }$ [10431-03-5]; NIST WebBook
    1-eicosoxy-2,3-propanediol $\ce{ C23H48O3 }$ [158850-88-5]; NIST WebBook
    1-heneicosoxy-2,3-propanediol $\ce{ C24H50O3 }$ [158789-24-3]; NIST WebBook
Experimental Data

Upper critical solution temperatures of the systems nitromethane (1) + alkyl glyceryl ether (2)

1-Alkyl glyceryl ethers (x17) $T$ (°C) $T$ ($\pu{K}$)
1-(cis,cis,cis-9,12,15-octadecatrienoxy)-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 52.5325.7
1-decoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 55.0328.2
1-Undecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 61.5334.7
1-(cis,cis-9,12-octadecadienoxy)-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 62.0335.2
1-dodecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 66.5339.7
1-(cis-9-hexadecenoxy)-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 68.0341.2
1-Tridecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 70.5343.7
1-Tetradecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 74.0347.2
1-(cis-9-octadecenoxy)-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 75.0348.2
1-(trans-9-octadecenoxy)-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 77.0350.2
1-pentadecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 77.5350.7
1-hexadecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 81.0354.2
1-heptadecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 84.0357.2
1-octadecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 87.5360.7
1-nonadecoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 90.5363.7
1-eicosoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 93.0366.2
1-heneicosoxy-2,3-propanediol (link to XML output link to JSON output link to JSON-LD output) 95.5368.7