Compilation - Nitromethane with 1-Alcohols (IUPAC SDS Volume 71)
SDS Volume (4263)
Volume 71. Nitromethane with Water or Organic Solvents, p 11298
Original Measurements
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 9, 134-144 (1965).
Variables:
Room Temp: 320 - 370 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The synthetic method was used. A Reichert microscope, type RCH, equipped with a heating stage was used as described in Schmid, et al. [1]. The disappearance and reappearance of the interface between (1) and (2) could be observed without difficulty.
Source and Purity of Materials:
- Fisher Scientific Co.; certified, No. N-98;
$n_{D}^{20}$ = \pu{1.3820}$, $\rho^{20} = \pu{1134 g L-1}$. - Some alcohols obtained from the Hormel Institute and from Lachat Chemicals; all other alcohols prepared by reduction of the corresponding methyl esters with lithium aluminum hydride; purified by gas-liquid partition chromatography.
Estimated Errors:
Upper Critical Solution Temperature: ±0.5 K.
References
1 Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
Components:
- Nitromethane $\ce{ CH3NO2 }$ [75-52-5]; NIST WebBook
-
1-Octanol $\ce{ C8H18O }$
[111-87-5];
NIST WebBook
1-Nonanol $\ce{ C9H20O }$ [143-08-8]; NIST WebBook
1-Decanol $\ce{ C10H22O }$ [112-30-1]; NIST WebBook
1-Undecanol $\ce{ C11H24O }$ [112-42-5]; NIST WebBook
1-Dodecanol $\ce{ C12H26O }$ [112-53-8]; NIST WebBook
1-Tridecanol $\ce{ C13H28O }$ [112-70-9]; NIST WebBook
1-Tetradecanol $\ce{ C14H30O }$ [112-72-1]; NIST WebBook
1-Pentadecanol $\ce{ C15H32O }$ [629-76-5]; NIST WebBook
1-Hexadecanol $\ce{ C16H34O }$ [36653-82-4]; NIST WebBook
1-Hexadecanol $\ce{ C16H34O }$ [1454-85-9]; NIST WebBook
1-Octadecanol $\ce{ C18H38O }$ [112-92-5]; NIST WebBook
1-Nonadecanol $\ce{ C19H40O }$ [1454-84-8]; NIST WebBook
1-Eicosanol $\ce{ C20H42O }$ [629-96-9]; NIST WebBook
Experimental Data
Upper critical solution temperatures of the systems nitromethane (1) with 1-alcohols (2)
| 1-Alcohols (C8-C20) | $t$ (°C) | $T$ ($\pu{K}$) |
|---|---|---|
1-Octanol
(
 )
|
46.5 | 319.7 |
|
1-Nonanol
(
)
|
52.0 | 325.2 |
|
1-Decanol
(
)
|
57.0 | 330.2 |
|
1-Undecanol
(
)
|
61.5 | 334.7 |
|
1-Dodecanol
(
)
|
66.0 | 339.2 |
|
1-Tridecanol
(
)
|
70.0 | 343.2 |
|
1-Tetradecanol
(
)
|
74.0 | 347.2 |
|
1-Pentadecanol
(
)
|
78.0 | 351.2 |
|
1-Hexadecanol
(
)
|
81.5 | 354.7 |
|
1-Hexadecanol
(
)
|
85.5 | 358.7 |
|
1-Octadecanol
(
)
|
89.0 | 362.2 |
|
1-Nonadecanol
(
)
|
93.0 | 366.2 |
|
1-Eicosanol
(
)
|
96.5 | 369.7 |