SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Zhuravleva, I. K.; Zhuravlev, E. F.; Sukhova, I. A.; Khisametdinova, Z. Z.; Zh. Fiz. Khim. 50, 405-10 (1976).
Conditions:
Room Temp: 323 - 357 $\pu{K}$
Compiler:
Methodology:
Solubility temperatures of the liquid or solid phase were determined by the synthetic method [1]. No further details were reported.
Sample Information:
- Source not specified; pure grade reagent; freshly distilled.
- Source not specified; pure grade reagent; freshly distilled.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.
Methodology Citation
1 Alekseev, V. F.; Zh. Russ. Fiz. -Khim. O-va 8, 249 (1876).
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- 1-Hexadecanol, $\ce{ C16H34O }$; [1454-85-9] NIST WebBook
Experimental Data
The mutual solubilities of nitromethane and 1-hexadecanol in mass percent over the specified temperature range were presented in graphical form in the original publication. The numerical data, in the table below, were provided by the authors at the request of the compiler.
Monotectic equilibrium is realized at 43.5°C (316.7 K, compiler).
| $T$ (°C) | $T$ ($\pu{K}$) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 50.0 | 323.2 | 10.4 | 0.316 |
| 50.0 | 323.2 | 97.2 | 0.993 |
| 60.0 | 333.2 | 15.9 | 0.429 |
| 60.0 | 333.2 | 96.0 | 0.990 |
| 70.0 | 343.2 | 23.1 | 0.544 |
| 70.0 | 343.2 | 92.9 | 0.981 |
| 80.0 | 353.2 | 36.0 | 0.691 |
| 80.0 | 353.2 | 89.8 | 0.972 |
| 83.5 | 356.7 | 66.0 | 0.885 |
| 83.5 | 356.7 | 66.0 | UCST |
