SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Zhuravleva, I. K.; Yamshanova, N. M.; Termicheskiy Analiz i Fazovye Ravnovesiya, Perm, 1985, pp. 109-15.
Conditions:
Room Temp: 304 - 345 $\pu{K}$
Compiler:
Methodology:
Solubility temperatures of the liquid phases were determined by the synthetic method [1]. No further experimental details given.
Sample Information:
- Source not specified; pure grade reagent; purified; $n_{D}^{20}$ = 1.3820, $\rho^{20} = \pu{1132.0 g L-1}$.
- Source not specified; purified; $n_{D}^{40}$ = 1.4373, $\rho^{40} = \pu{822.3 g L-1}$.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.
Methodology Citation
1 Alekseev, V. F.; Zh. Russ. Fiz. -Khim. O-va 8, 249 (1876).
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- 1-Tridecanol, $\ce{ C13H28O }$; [112-70-9] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 30.9 | 304.1 | 6.1 | 0.175 |
| 30.9 | 304.1 | - | - |
| 36.4 | 309.6 | 8.0 | 0.219 |
| 36.4 | 309.6 | - | - |
| 38.2 | 311.4 | 8.2 | 0.226 |
| 38.2 | 311.4 | - | - |
| 45.8 | 319.0 | - | - |
| 45.8 | 319.0 | 94.8 | 0.984 |
| 51.6 | 324.8 | 15.6 | 0.376 |
| 51.6 | 324.8 | - | - |
| 54.8 | 328.0 | - | - |
| 54.8 | 328.0 | 92.4 | 0.975 |
| 58.8 | 332.0 | 19.6 | 0.443 |
| 58.8 | 332.0 | - | - |
| 61.3 | 334.5 | - | - |
| 61.3 | 334.5 | 86.9 | 0.956 |
| 62.4 | 335.6 | 23.3 | 0.498 |
| 62.4 | 335.6 | - | - |
| 66.4 | 339.6 | 29.8 | 0.581 |
| 66.4 | 339.6 | - | - |
| 67.1 | 340.3 | - | - |
| 67.1 | 340.3 | 82.8 | 0.940 |
| 68.6 | 341.8 | 34.4 | 0.631 |
| 68.6 | 341.8 | - | - |
| 69.6 | 342.8 | - | - |
| 69.6 | 342.8 | 75.4 | 0.909 |
| 70.9 | 344.1 | 43.9 | 0.719 |
| 70.9 | 344.1 | - | - |
| 71.1 | 344.3 | - | - |
| 71.1 | 344.3 | 69.2 | 0.880 |
| 71.2 | 344.4 | - | - |
| 71.2 | 344.4 | 60.5 | 0.833 |
| 71.3 | 344.5 | 54.4 | 0.796 |
| 71.3 | 344.5 | 54.4 | UCST |
