SDS Volume

Volume 71. Nitromethane with Water or Organic Solvents, p None

Source Publication

Sazonov, V. P.; Filippov, V. V.; Izv. Vyssh. Uchebn. Zaved.; Khim. Khim. Tekhnol. 18, 222-5(1975).

Conditions:

Room Temp: 291 - 341 $\pu{K}$

Compilers:

N.V. Sazonov, V.P. Sazonov

Methodology:

The synthetic (Alekseev ) method was used. Close to the phase transition temperature, heating and cooling of mixtures were accomplished in steps at a rate of 0.02 K/h.

Sample Information:
  1. Source not specified; pure grade reagent; distilled through a column of 15 theoretical plates; $n_{D}^{20}$ = 1.3819, $\rho^{20} = \pu{1138.1 g L-1}$.
  2. Source not specified; pure grade reagent; fractionally distilled at about 400 Pa.
Measurement Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.

System Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. 1-Dodecanol, $\ce{ C12H26O }$; [112-53-8] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) w1 $x_{1}$
18.20291.35 4.50 0.1258
18.20291.35 - -
31.75304.90 - -
31.75304.90 97.23 0.9907
42.75315.90 - -
42.75315.90 94.62 0.9817
48.95322.10 10.0 0.2533
48.95322.10 - -
57.60330.75 - -
57.60330.75 89.61 0.9634
60.02333.17 - -
60.02333.17 84.96 0.9452
62.25335.40 25.00 0.5044
62.25335.40 - -
63.95337.10 - -
63.95337.10 79.97 0.9242
65.25338.40 29.99 0.5667
65.25338.40 - -
66.37339.52 - -
66.37339.52 75.04 0.9018
66.77339.92 36.94 0.6413
66.77339.92 - -
67.37340.52 40.0 0.6705
67.37340.52 - -
67.52340.67 - -
67.52340.67 70.05 0.8772
67.77340.92 44.99 0.7140
67.77340.92 - -
67.97341.12 49.97 0.7530
67.97341.12 - -
68.02341.17 54.97 0.7884
68.02341.17 - -
68.03341.18 - -
68.03341.18 65.01 0.8501
68.17341.32 - -
68.17341.32 60.02 0.8208
68.18341.33 55.80 0.7940
68.18341.33 55.80 UCST

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