SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Francis, A. W.; J. Phys. Chem. 60, 20-7 (1956).
Conditions:
Room Temp: 289 - 336 $\pu{K}$
Compiler:
Methodology:
Observations were made after vigorous shaking in glass-stoppered graduated tubes of 15 mL capacity, immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding cooler or warmer water occasionally.
Sample Information:
- Eastman Kodak Co., distilled through a 30 cm column; BP = 101.25°C, MP = -30.5°C, $n_{D}^{20}$ = 1.3820, $\rho^{25} = \pu{1129.8 g L-1}$.
- Source not specified; purified by crystallization; MP = 22.7°C, $n_{D}^{20}$ = 1.4410, $\rho^{24} = \pu{832 g L-1}$.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- 1-Dodecanol, $\ce{ C12H26O }$; [112-53-8] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 16.0 | 289.2 | - | - |
| 16.0 | 289.2 | 98.0 | 0.993 |
| 22.0 | 295.2 | 3.0 | 0.09 |
| 22.0 | 295.2 | 97.0 | 0.990 |
| 28.0 | 301.2 | 7.0 | 0.19 |
| 28.0 | 301.2 | 96.0 | 0.987 |
| 29.0 | 302.2 | 8.0 | 0.21 |
| 29.0 | 302.2 | 96.0 | 0.987 |
| 63.0 | 336.2 | 53.0 | 0.78 |
| 63.0 | 336.2 | 53.0 | UCST |


