SDS Volume

Volume 71. Nitromethane with Water or Organic Solvents, p None

Source Publication

Francis, A. W.; J. Phys. Chem. 60, 20-7 (1956).

Conditions:

Room Temp: 289 - 336 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

Observations were made after vigorous shaking in glass-stoppered graduated tubes of 15 mL capacity, immersed in water baths in large Dewar flasks. The water was agitated with a rapid stream of air bubbles. The temperature was adjusted by adding cooler or warmer water occasionally.

Sample Information:
  1. Eastman Kodak Co., distilled through a 30 cm column; BP = 101.25°C, MP = -30.5°C, $n_{D}^{20}$ = 1.3820, $\rho^{25} = \pu{1129.8 g L-1}$.
  2. Source not specified; purified by crystallization; MP = 22.7°C, $n_{D}^{20}$ = 1.4410, $\rho^{24} = \pu{832 g L-1}$.
Measurement Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.

System Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. 1-Dodecanol, $\ce{ C12H26O }$; [112-53-8] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) 100w1 $x_{1}$
16.0289.2 - -
16.0289.2 98.0 0.993
22.0295.2 3.0 0.09
22.0295.2 97.0 0.990
28.0301.2 7.0 0.19
28.0301.2 96.0 0.987
29.0302.2 8.0 0.21
29.0302.2 96.0 0.987
63.0336.2 53.0 0.78
63.0336.2 53.0 UCST

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