Compilation - Nitromethane with Water (IUPAC SDS Volume 71)
SDS Volume (4235)
Volume 71. Nitromethane with Water or Organic Solvents, p None
Original Measurements
Stephenson, R. M.; J. Chem. Eng. Data 37, 80-95 (1992).
Variables:
Room Temp: 273 - 363 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
No details were reported.
Source and Purity of Materials:
- Aldrich Chemical; not purified; purity more 99 mass%.
- Twice distilled.
Estimated Errors:
Ambient temperature: to ±0.1 K.
Mass concentration (m/v) (1): ±0.2% (1) in (2), ±0.05% (2) in (1).
Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Mutual solubility of nitromethane and water
| $T$ (°C) | $T$ ($\pu{K}$) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 0 | 273.2 | 9.0 | 0.028 |
| 0 | 273.2 | 98.9 | 0.964 |
| 9.5 | 282.8 | 9.7 | 0.031 |
| 9.5 | 282.8 | 98.56 | 0.9528 |
| 19.7 | 292.9 | 10.4 | 0.0331 |
| 19.7 | 292.9 | 98.09 | 0.9381 |
| 31.0 | 304.2 | 11.7 | 0.0376 |
| 31.0 | 304.2 | 97.50 | 0.9201 |
| 40.4 | 313.6 | 12.8 | 0.0415 |
| 40.4 | 313.6 | 96.35 | 0.8863 |
| 50.0 | 323.2 | 14.8 | 0.0488 |
| 50.0 | 323.2 | 93.87 | 0.8189 |
| 60.5 | 333.7 | 15.1 | 0.0499 |
| 60.5 | 333.7 | 92.08 | 0.7744 |
| 70.5 | 343.7 | 17.1 | 0.0574 |
| 70.5 | 343.7 | 91.82 | 0.7682 |
| 80.2 | 353.4 | 19.6 | 0.0671 |
| 80.2 | 353.4 | 89.58 | 0.7174 |
| 89.8 | 363.0 | 20.8 | 0.0720 |
| 89.8 | 363.0 | - | - |
