SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Sazonov, V. P.; Zh. Obshch. Khim. 59, 2431-5 (1989).
Conditions:
Room Temp: 294 - 339 $\pu{K}$
Compilers:
Methodology:
The synthetic method of Alekseev was used. The apparatus which employs visual indication of turbidity was described by Sazonov and Chernysheva [1]. No further details were reported.
Sample Information:
- Source not specified; pure grade reagent; fractionally distilled; 99.85 mass% purity; $n_{D}^{20}$ = 1.3819, $\rho^{20} = \pu{1138.0 g L-1}$.
- Twice distilled.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.
Methodology Citation
1 Sazonov, V. P.; Chernysheva, M. F.; Zh. Obshch. Khim. 57, 46-54 (1987).
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | w1 | $x_{1}$ |
|---|---|---|---|
| 21.0 | 294.2 | 10.7 | 0.0342 |
| 21.0 | 294.2 | 97.9 | 0.932 |
| 23.3 | 296.5 | 11.0 | 0.0352 |
| 23.3 | 296.5 | - | - |
| 29.0 | 302.2 | - | - |
| 29.0 | 302.2 | 97.5 | 0.920 |
| 30.0 | 303.2 | 11.8 | 0.0380 |
| 30.0 | 303.2 | - | - |
| 32.4 | 305.6 | 12.0 | 0.0387 |
| 32.4 | 305.6 | - | - |
| 36.1 | 309.3 | - | - |
| 36.1 | 309.3 | 97.0 | 0.905 |
| 39.6 | 312.8 | 13.0 | 0.0422 |
| 39.6 | 312.8 | - | - |
| 40.0 | 313.2 | 13.3 | 0.0433 |
| 40.0 | 313.2 | - | - |
| 42.0 | 315.2 | - | - |
| 42.0 | 315.2 | 96.4 | 0.888 |
| 46.2 | 319.4 | 14.0 | 0.0459 |
| 46.2 | 319.4 | - | - |
| 46.4 | 319.7 | - | - |
| 46.4 | 319.7 | 96.0 | 0.876 |
| 54.0 | 327.2 | - | - |
| 54.0 | 327.2 | 95.1 | 0.851 |
| 65.7 | 338.9 | - | - |
| 65.7 | 338.9 | 93.7 | 0.815 |
