Compilation - Hexane with Water (IUPAC SDS Volume 37)
SDS Volume (420)
Volume 37. Hydrocarbons in Water and Seawater, Part I, p 350
Original Measurements
Sultanov, R. G.; Skripka, V. G.; Zh. Fiz. Khim. 1973, 47, 1035.
Skripka, V. G.; Tr. Vses. Neftegazov. Nauch. Issled. Inst. 1976, 61, 139-51.
Variables:
Room Temp:
200 and 220
°C
Pressure:
3.6 - 78.5
$\pu{MPa}$
Prepared by:
Method/Apparatus/Procedure:
The experimental technique was described in [1]. No details reported in the paper.
Source and Purity of Materials:
- source not specified, chemical reagent grade; purity not received.
- Distilled.
Estimated Errors:
Ambient temperature: Not specified.
References
1 Sultanov, R. G.; Skripka, V. G.; Namiot, Yu. A.; Gazov. Prom. 1971, 4, 6.
Components:
- Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Solubility of water in hexane
| $T$ (°C) | $P$ ($\pu{kg/cm2}$) | $P$ ($\pu{MPa}$) | $x_{2}$ | MR2 (g2/100 g sln) |
|---|---|---|---|---|
| 200 | 37 | 3.6 | 0.097 | 2.20 |
| 200 | 50 | 4.9 | 0.094 | 2.12 |
| 200 | 100 | 9.8 | 0.084 | 1.88 |
| 200 | 200 | 19.6 | 0.072 | 1.60 |
| 200 | 300 | 29.4 | 0.065 | 1.43 |
| 200 | 400 | 39.2 | 0.060 | 1.32 |
| 200 | 500 | 49.0 | 0.055 | 1.20 |
| 200 | 600 | 58.8 | 0.051 | 1.11 |
| 200 | 700 | 68.6 | 0.047 | 1.02 |
| 200 | 800 | 78.5 | 0.041 | 0.89 |
| 220 | 50.8 | 5.0 | 0.187 | 4.59 |
| 220 | 80 | 8.3 | 0.145 | 3.42 |
| 220 | 100 | 9.8 | 0.134 | 3.13 |
| 220 | 200 | 19.6 | 0.113 | 2.59 |
| 220 | 300 | 29.4 | 0.102 | 2.32 |
| 220 | 400 | 39.2 | 0.092 | 2.07 |
| 220 | 500 | 49.0 | 0.083 | 1.86 |
| 220 | 600 | 58.8 | 0.074 | 1.64 |
| 220 | 700 | 68.6 | 0.068 | 1.50 |
| 220 | 800 | 78.5 | 0.065 | 1.43 |
