SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Malesinska, B.; Bull. Acad. Pol. Sci.; Ser. Sci. Chim. 8, 53 (1960).
Conditions:
Room Temp: 375 - 404 $\pu{K}$
Compiler:
Methodology:
The synthetic (Alekseev) method was used. Sealed samples, about 1.0 - 1.5 g, of various compositions were heated to a temperature higher than that required for complete homogeneity, then cooled at about 0.01 K/min until turbidity and a meniscus appeared. Repeat determinations were made.
Sample Information:
- Source not specified; purity not specified; dried and twice distilled.
- Isolated from a Fischer-Tropsch gasoline fraction freed from unsaturated hydrocarbons; fractionally distilled.
Measurement Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- Undecane, $\ce{ C11H24 }$; [1120-21-4] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | 100w1 |
|---|---|---|---|
| 101.50 | 374.65 | 0.2930 | 13.93 |
| 101.50 | 374.65 | - | - |
| 114.55 | 387.70 | 0.4022 | 20.81 |
| 114.55 | 387.70 | - | - |
| 118.50 | 391.65 | 0.4443 | 23.79 |
| 118.50 | 391.65 | - | - |
| 119.19 | 392.34 | - | - |
| 119.19 | 392.34 | 0.9321 | 84.28 |
| 125.57 | 398.72 | - | - |
| 125.57 | 398.72 | 0.9002 | 77.89 |
| 127.70 | 400.85 | 0.5966 | 36.61 |
| 127.70 | 400.85 | - | - |
| 129.90 | 403.05 | 0.7006 | 47.75 |
| 129.90 | 403.05 | - | - |
| 130.18 | 403.33 | - | - |
| 130.18 | 403.33 | 0.8008 | 61.09 |
| 130.20 | 403.35 | - | - |
| 130.20 | 403.35 | 0.7915 | 59.72 |
| 130.38 | 403.53 | 0.7582 | 55.05 |
| 130.38 | 403.53 | - | - |
| 130.40 | 403.55 | 0.7700 | 56.70 |
| 130.40 | 403.55 | 0.7700 | UCST |
