SDS Volume (416)

Volume 37. Hydrocarbons in Water and Seawater, Part I, p 346

Original Measurements

Mackay, D.; Shiu, W. Y.; Wolkoff, A. W.; "Water Quality Parameters" Symp. 1973, ASTM Spec. Tech. Publ. 1975, 573, 251-8.

Variables:

Temperature: Not specified

Prepared by:

M.C. Haulait-Pirson

Method/Apparatus/Procedure:

(1) is partially partitioned into the vapor phase by equilibration of the aqueous sample with helium in a gas syringe, the vapor then being transferred to a gas sampling valve and then to a column of a gas chromatograp equipped with a flame ionization detector. By injecting gas samples from repeated equilibrations it is possible to calculate the amount of (1) in the original sample.

Source and Purity of Materials:
  1. Not specified.
  2. Not specified.

Hexane with Water

Components:

(1) Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
(2) Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Values:

The authors reported the value of 16.2 mg(1)/dm-3 sln for the solubility of hexane in water. With the assumption of a solution density of 1.00 g cm-3, the corresponding mass percent, calculated by the compiler, is 0.00162 g(1)/100 g sln and the corresponding mole fraction, x1, is 3.4 × 10-6.

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