Compilation - Nitromethane with Water (IUPAC SDS Volume 71)
SDS Volume (4147)
Volume 71. Nitromethane with Water or Organic Solvents, p None
Original Measurements
Schuberth, H.; Kranke, P.; Z. Phys. Chem. 245O, 49-67 (1970).
Variables:
Room Temp: 293 - 333 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The synthetic method and the titration method were used. No further details were reported.
Source and Purity of Materials:
- Source not specified; pure grade reagent; distilled; BP = 101.0°C, $n_{D}^{20}$ = 1.38195, $\rho^{20} = \pu{1137.9 g L-1}$.
- distilled.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Mutual solubility of nitromethane and water
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | 100w1 |
|---|---|---|---|
| 20.0 | 293.2 | 0.034 | 10.6 |
| 20.0 | 293.2 | 0.936 | 98.0 |
| 30.0 | 303.2 | 0.038 | 11.8 |
| 30.0 | 303.2 | 0.916 | 97.4 |
| 40.0 | 313.2 | 0.043 | 13.2 |
| 40.0 | 313.2 | 0.893 | 96.6 |
| 50.0 | 323.2 | 0.049 | 14.9 |
| 50.0 | 323.2 | 0.865 | 95.6 |
| 60.0 | 333.2 | 0.057 | 17.0 |
| 60.0 | 333.2 | 0.827 | 94.2 |
