SDS Volume (413)

Volume 37. Hydrocarbons in Water and Seawater, Part I, p 343

Original Measurements

Krasnoschchekova, R. Ya.; Gubergrits, M. Ya.; Neftekhimiya 1973, 13, 885-8.

Variables:

Temperature: 25 °C

Prepared by:

A. Maczynski

Method/Apparatus/Procedure:

A mixture of 10 mL (1) and 300 mL (2) was placed in a double-walled bottom stoppered vessel and vigorously stirred magnetically for 10-12 hr. The phases were allowed to separate; a first sample of the water phase was rejected and next 200 mL of this phase was rejected and next 200 mL of this phase was taken, 20-mL aliquots were introduced into 40-mL hermetic bottles and (1) was allowed to equilibrate with the air, and the (1)-saturated air was analyzed by glc.

Source and Purity of Materials:
  1. source not specified; CP reagent; purity not specified.
  2. Distilled.

Hexane with Water

Components:

(1) Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
(2) Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Values:

The solubility of hexane in water at 25°C was reported to be x1 = 2.8 × 10-6.
The corresponding mass percent calculated by the compiler is 1.3 × 10-3 g(1)/100 g sln.

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