Components:
(1) Xenon,
Xe; [7440-63-3]
NIST WebBook
(2) Poly(vinyltrimethyl silane),
(C5H12Si)n; [25036-32-2]
NIST WebBook
Original Measurements
Variables:
Ambient temperature: 293 - 313 K
Pressure: 0 - 93 kPa
Prepared by:
Method/Apparatus/Procedure:
A McBain balance with a quartz spring was used in sorption measurement.
Source and Purity of Materials:
- PVTMS synthesized in the presence of BuLi had Mw = 608,000 and Mn = 416,000. All the gases were chromatographically pure.
Estimated Errors:
Mass concentration (m/v) (1): 10%.
Experimental Values:
Solubility coefficients S/(cm3(STP)/cm3 atm) at 298 K and enthalpies of sorption ΔH kcal/mol
| β (cm3(g) cm-3(s) atm-1) | ΔH (kcal/mol) |
|---|---|
| 7.1 x 10-2 | 4.2 |
| 3.3 x 10-2 | - |
| 4.7 x 10-2 | 4.02 |
| 7.0 x 10-2 | 3.58 |
| 3.15 x 10-1 | 5.47 |
| 3.0 x 10-1 | 5.64 |
| 3.1 x 10-1 | 5.96 |
| 4 x 10-1 | 6.2 |
| 2.72 | - |
