Components:
(1) Carbon dioxide,
CO2; [124-38-9]
NIST WebBook
(1) Methane,
CH4; [74-82-8]
NIST WebBook
(2) Polystyrene,
(C8H8)n; [9003-53-6]
NIST WebBook
Original Measurements
Variables:
Ambient temperature: 293 - 313 K
Pressure: 0.2 - 3.0 MPa
Prepared by:
Method/Apparatus/Procedure:
Equilibrium sorption was measured by the pressure decay method in the cell similar to that described in ref. (1). The pressure in the cell was continuously measured by a pressure transducer.
Source and Purity of Materials:
- PS films provided by Mitzubishi -Monsanto Chemical Co were studied.
References
1 Koros, W. J.; Paul, D. R.; Rocha, A. A.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 687.
Experimental Values:
Dual mode sorption parameters
| T (K) | H (cm3(g) cm-3(s) atm-1) | C'H (cm3/cm3) | b (atm-1) |
|---|---|---|---|
| 293.0 | 8.01 x 10-1 | 13.0 | 1.84 x 10-1 |
| 303.0 | 7.13 x 10-1 | 11.0 | 1.34 x 10-1 |
| 313.0 | 5.86 x 10-1 | 8.81 | 9.18 x 10-2 |
| 293.0 | 3.05 x 10-1 | 5.0 | 8.11 x 10-2 |
| 303.0 | 2.77 x 10-1 | 4.93 | 6.23 x 10-2 |
| 313.0 | 2.44 x 10-1 | 3.63 | 4.39 x 10-2 |
