Compilation - Hydrocarbons C1-C3 with Statistical co-polymer of 2,6-dimethyl- and 2,6-diphenyl-1,4-phenylene oxide (IUPAC SDS Volume 70)
SDS Volume (4043)
Volume 70. Solubility of Gases in Glassy Polymers , p None
Original Measurements
Ilinitch, O. M.; Semin, G. L.; Chertova, M. V.; Zamaraev, K. I.; J. Membr. Sci. 66, 1-8 (1992).
Variables:
Temperature:
293.2
K
Pressure:
0 - 100
MPa
Percent mole fraction - Liquid (2):
100x2 = 97.5%
Percent mole fraction - Liquid (3):
100x3 = 2.5%
Prepared by:
Method/Apparatus/Procedure:
The conventional McBain sorption spring balance was used.
Source and Purity of Materials:
- The copolymer was prepared via oxidative copolycondensation of two monomers. The purity of product 99.9%, it had density 1.10 g/cm3 and Tg =754K. All the gases had a purity >99.9%.
Experimental Data
Hydrocarbons (C1-C3) with Poly(2,6-dimethyl-1,4-phenyleneoxide)/Poly(2,6-diphenyl-1,4-phenyleneoxide) Copolymer
Components:
(1) Ethane,
$\ce{ C2H6 }$;
[74-84-0]
NIST WebBook
(1) Propene,
$\ce{ C3H6 }$;
[115-07-1]
NIST WebBook
(1) Propane,
$\ce{ C3H8 }$;
[74-98-6]
NIST WebBook
(1) Methane,
$\ce{ CH4 }$;
[74-82-8]
NIST WebBook
(2) Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO),
$\ce{ (C8H8O)n }$;
[24938-67-8]
NIST WebBook
Experimental Values:
Solubility C /cm3 (STP) cm-3 of hydrocarbons in the copolymer
| P1 (kPa) | S (cm3(g) cm-3(s) atm-1) |
|---|---|
| 28.0 | 6 x 10-1 |
| 34.7 | 4 x 10-1 |
| 50.0 | 7 x 10-1 |
| 66.6 | 1.2 |
| 86.6 | 1.4 |
| 96.0 | 1.5 |
| 3.3 | 2.8 |
| 6.3 | 3.6 |
| 9.6 | 4.3 |
| 13.3 | 5.1 |
| 18.7 | 5.8 |
| 24.0 | 6.6 |
| 29.3 | 7.3 |
| 29.3 | 4.9 |
| 33.3 | 5.5 |
| 34.4 | 7.9 |
| 40.0 | 8.4 |
| 46.7 | 9.4 |
| 53.3 | 10.2 |
| 61.3 | 11.2 |
| 2.7 | 9 x 10-1 |
| 5.3 | 1.6 |
| 8.0 | 2.2 |
| 10.7 | 2.6 |
| 13.3 | 2.9 |
| 17.3 | 3.4 |
| 21.3 | 3.8 |
| 25.3 | 4.4 |
| 1.6 | 2.0 |
| 4.0 | 2.9 |
| 6.7 | 4.0 |
| 10.6 | 4.9 |
| 14.0 | 5.6 |
| 20.0 | 6.8 |
| 26.7 | 7.6 |
| 33.3 | 9.0 |
| 38.7 | 9.6 |
| 53.3 | 11.5 |
