Compilation - Chlorobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (40)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 158
Original Measurements
Gross, P. M.; Saylor, J. H.; J. Am. Chem. Soc. 1931, 53, 1744-51.
Variables:
Room Temp: 30 °C
Prepared by:
Method/Apparatus/Procedure:
An excess of chlorobenzene in 500 g water was shaken for 12 hours in a thermostat bath. Samples were then withdrawn and read against water as a reference using an interferometer made by Zeiss [1]. A detailed description of the complete procedure has been described in a Ph.D. dissertation [2].
Source and Purity of Materials:
- Eastman Kodak Co., was purified by fractional distillation before use.
- Distilled.
Estimated Errors:
Ambient temperature: ±0.02 K.
Mass concentration (m/v) (1): ±1.0%.
References
1
Gross, P. M.; J. Am. Chem. Soc. 1929, 51, 2362-6.
2
Saylor, J. H.; Ph.D. Dissertation, Duke University, Durham, NC, 1930.
Components:
- Chlorobenzene, $\ce{ C6H5C1 }$; [108-90-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | MR1 (g/kg) | m1 (mol/kg) |
|---|---|---|---|
| 30 | 7.810 x 10-5 | 0.488 | 4.333 x 10-3 |
(a) Reported.
(b) Calculated by F. W. Getzen.
(c) Calculated by the compiler.
