Components:

(1) Helium, He; [7440-59-7] NIST WebBook
(1) Neon, None; [7440-01-9] NIST WebBook
(1) Argon, Ar; [7440-37-1] NIST WebBook
(1) Krypton, Kr; [7439-90-9] NIST WebBook
(1) Nitrogen (Molecule), N2; [7727-37-9] NIST WebBook
(1) Carbon dioxide, CO2; [124-38-9] NIST WebBook
(2) Poly(methyl methacrylate), (C17H23NO6)n; [9011-14-7] NIST WebBook

Original Measurements

Durill, P. L.; Ph.D. Dissertation, Virginia Polytech. Inst. (1965).
Durill, P. L.; Griskey, R. G.; AIChE. Journal 12, 1147-51 (1966).

Variables:

Ambient temperature: 461 K
Pressure: 0.26 - 1.9 MPa (2.6 - 19 atm)

Prepared by:

A.K. Bokarev

Method/Apparatus/Procedure:

The equipment and a manometrical procedure for solubility measurements were similar to those of Lundberg et al.1

Source and Purity of Materials:
  1. PMMA (Lucite) used is a product of du Pont de Nemours Co.: ρ = 1.20 g/cm3.
    Gases from Air Reduction Co., had a minimum purity: CO2 - 99.5%; N2 - 99.90%; Ar - 99.997%; He - 99.99%.
    Gases (Matheson Co), included as impurities: Ne-14 ppm He, Kr-12 ppm N2 and 23 ppm Xe.
Estimated Errors:

Mass concentration (m/v) (1): δC/C ≤ 8%.

References

1 Lundberg, J. L.; Wilk, M. B.; Huyett, M. J.; J. Appl. Phys., 1960, 31, 1131.

Experimental Values:
Henry's law solubility constants for S for gases in PMMA
P (atm) β (cm3(g)/g(s) atm-1)
3.8-7.2 6.6 x 10-2
2.7 1.26 x 10-1
3.2-7.4 1.05 x 10-1
2.6-4.6 1.22 x 10-1
5.7-15.0 4.5 x 10-2
4.0-19.0 2.60 x 10-1

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