SDS Volume
Volume 70. Solubility of Gases in Glassy Polymers, p None
Source Publication
Durrill, P. L.; Ph.D. Dissertation, Virginia Polytech. Inst. (1965).
Durrill, P. L.; Griskey, R. G.; AIChE. Journal 12, 1147-51 (1966).
Conditions:
Room Temp:
461
$\pu{K}$
Pressure:
0.26 - 1.9
$\pu{MPa}$
Compiler:
Methodology:
The equipment and a manometrical procedure for solubility measurements were similar to those of Lundberg, et al. [1]
Sample Information:
- Gases from Air Reduction Co., had a minimum purity:
$\ce{CO2} - \pu{99.5\%}$; $\ce{N2} - \pu{99.90\%}$; $\ce{Ar} - \pu{99.97\%}$; $\ce{He} - \pu{99.99\%}$.
Gases (Matheson Co), included as impurities:
$\ce{Ne}$: 14 ppm $\ce{He}$, $\ce{Kr}$: $\pu{12 ppm}\ \ce{N2}$ and $\pu{23 ppm}\ \ce{Xe}$. - PMMA (Lucite) used is a product of du Pont de Nemours Co.: $\rho = \pu{1.20 g mL-1}$.
Measurement Errors:
Mass concentration (m/v) (1): δC/C ≤ 8%.
Methodology Citation
1 Lundberg, J. L.; Wilk, M. B.; Huyett, M. J.; J. Appl. Phys., 1960, 31, 1131.
System Components:
- Helium, $\ce{ He }$; [7440-59-7] NIST WebBook
- Neon, $\ce{ Ne }$; [7440-01-9] NIST WebBook
- Argon, $\ce{ Ar }$; [7440-37-1] NIST WebBook
- Krypton, $\ce{ Kr }$; [7439-90-9] NIST WebBook
- Nitrogen (Molecule), $\ce{ N2 }$; [7727-37-9] NIST WebBook
- Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
- Poly(methyl methacrylate) (PMMA), $\ce{ (C17H23NO6)n }$; [9011-14-7] NIST WebBook
Experimental Data
| $P$ ($\pu{atm}$) | $S$ ($\pu{cm3(g) g-1(s) atm-1}$) |
|---|---|
| 3.8-7.2 | 0.066 |
| 2.7 | 0.126 |
| 3.2-7.4 | 0.105 |
| 2.6-4.6 | 0.122 |
| 5.7-15.0 | 0.045 |
| 4.0-19.0 | 0.260 |
