SDS Volume

Volume 37. Hydrocarbons in Water and Seawater, Part I, p 329

Source Publication

McCants, J. F.; Jones, J. H.; Hopson, W. H.; Ind. Eng. Chem. 1953, 45, 454-6.

Conditions:

Room Temp: One temperature: 100 °F (311 K) °F

Compiler:

G.T. Hefter

Methodology:

The method was essentially that of [1] and involved titration of the second component to the cloud point, in a constant temperature bath.

Sample Information:
  1. Phillips; pure grade; used without further purification; $n_{D}^{20}$ = 1.3752.
  2. Distilled.
Measurement Errors:

Ambient temperature: Not specified.

Methodology Citation

1 Washburn, E. R.; Hnizda, V.; Vold, R.; J. Am. Chem. Soc. 53, 3237 (1931).

System Components:
  1. Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data

The solubility of n-hexane in water at 100°F (311 K) was reported to be < 0.1 g(1)/100 g sln. The corresponding mole fraction, x2, calculated by the compiler, is < 2 × 10-4.
The solubility of water in n-hexane at 100°F (311 K) was reported to be < 0.1 g(2)/100 g sln. The corresponding mole fraction, x2, calculated by the compiler, is < 5 × 10-3.

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