SDS Volume (395)

Volume 37. Hydrocarbons in Water and Seawater, Part I, p 327

Original Measurements

Durand, R.; C. R. Hebd. Seances Acad. Sci. 1948, 226, 409-10.

Variables:

Temperature: 16 °C

Prepared by:

M.C. Haulait-Pirson

Method/Apparatus/Procedure:

The thermostatic method described in [1] was used. Addition of pipetted volumes of (1) to (2) followed by shaking is repeated till appearance of turbidity.

Source and Purity of Materials:
  1. Not specified.
  2. Distilled.
References

1 Durand, R.; C. R. Hebd. Seances Acad. Sci. 1946, 223, 898-900.
2 Timmermans, J.; Physico-Chemical Constants of Pure Organic Compounds (Elsevier, New York, 1950).

Hexane with Water

Components:

(1) Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
(2) Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Values:

The solubility of hexane in water at 16°C was reported to be 0.055 cm3(1)/dm3(2).
With the assumption of a solution density of 1.00 g cm-3 and a density value of 0.6629 g cm-3 for hexane at 16°C (ref 2), the corresponding mass percent is 0.0036 g(1)/100 g sln and the corresponding mole fraction, x1, is 7.5 × 10-6 (compiler).

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