SDS Volume (3903)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Arzhanov, P. G.; Komarova, L. F.; Garber, Yu. N.; Zh. Prikl. Khim. 48, 2089 (1975).

Variables:

Room Temp: 348 - 353 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

The analytical method was used. The equilibrium was investigated at the boiling temperature at 760 Torr. The samples were taken for GLC analysis through heated capillaries. Analysis: column 2 m long and 4 mm diameter filled with polichrom with 15% polyethyleneglycoladipinate; 100 °C; $\ce{H2}$ 100 mL/min; internal standard and homogenizer-acetone. Boiling temperatures of the two-phase mixture at 760 Torr. were estimated from the authors' graph.

Source and Purity of Materials:

1. Source not specified; purified in the laboratory; BP = $\pu{78.3 \pm 0.1^{\circ}C}$, $n_{D}^{20}$ = 1.3614; the properties were in agreement with literature data, purity was checked by GLC analysis.
2. Source not specified; purified in the laboratory; BP = 110.7±0.1°C, $n_{D}^{20}$ = 1.4969; the properties were in agreement with literature data, purity was checked by GLC analysis.
3. Double distilled.

Estimated Errors:

Ambient temperature: Pressure ±0.1 Torr.
Mass concentration (m/v) (1): Not reported.