SDS Volume (3892)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Bonner, W. D.; J. Phys. Chem. 14, 738 (1909).

Variables:

Room Temp: 273 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

In a tube 1 cm diam and 12 cm long known amount, by weight, of hydrocarbon and water were placed into a temperature controlled bath. The contents of the tube were stirred and alcohol was added gradually until a homogeneous solution was obtained. Observations were made visually through the telescope of a cathetometer. The samples were always weighed immediately before and after each experiment. Concentrations were reported as weight of water in 1 g of binary water-hydrocarbon mixture and the weight of alcohol necessary to make a homogeneous solution. The mass of binary water-hydrocarbon mixture was about 1 g; the mass of alcohol-up to 5 g.

Source and Purity of Materials:
  1. Kahlbaum; presumably dried and distilled.
  2. Kahlbaum; presumably dried and distilled; $n^{14}$ = 1.38382.
  3. Source not specified.
Estimated Errors:

Ambient temperature: Accuracy of weighting 0.0001 g.
Mass concentration (m/v) (1): Not reported.

Components:
  1. Ethanol, $\ce{ C2H6O }$; [64-17-5] NIST WebBook
  2. Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Compositions along the saturation curve
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
0.0273.2 0.37110.61010.49780.4375
0.0273.2 0.39020.58840.51390.4142
0.0273.2 0.62120.32800.67060.1893
0.0273.2 0.65510.28530.68220.1588
0.0273.2 0.70720.21320.69010.1112
0.0273.2 0.73060.16460.67240.0810
0.0273.2 0.74750.11990.64960.0557
0.0273.2 0.75000.10620.63860.0484
0.0273.2 0.74480.07610.59890.0327
0.0273.2 0.73120.04970.55480.0202
0.0273.2 0.69490.03200.49280.0121
0.0273.2 0.51366.8 x 10-30.29462.1 x 10-3

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