SDS Volume (3883)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Tarasenkov, D. N.; Paulsen, I. A.; Acta Physicochim. URSS 11, 75 (1939).

Variables:

Room Temp: 273 - 298 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

A titration method similar to that in [1] was used. A flask of 100 mL capacity containing a binary cyclohexane-alcohol mixture of known composition, by weight, was placed in a thermostat. The mixture was titrated with water from a microburette with a scale of 0.01 mL, until opalescence, emulation or turbidity was observed. Samples of the same binary composition were titrated several times.

Source and Purity of Materials:

1. Source not specified; purity of 99.97% for three points of the lower alcohol concentration at each temperature and purity of 92.64% for all other points.
2. Source not specified; distilled; BP = 80.9°C, $d_{4}^{20}$ = 0.7744.
3. Source not specified.

Estimated Errors:

Ambient temperature: Temp. ±0.05°C.
Mass concentration (m/v) (1): Not reported.

References

¹ Washburn, E. R.; Hnizda, V.; Vold, R.; J. Am. Chem. Soc. 53, 3237 (1931).