Compilation - Methanol with Benzene and Water (IUPAC SDS Volume 69)

SDS Volume (3871)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Sata, N.; Kimura, O.; Bull. Chem. Soc. Jpn. 10, 409-20 (1935).

Variables:

Room Temp: 292 - 304 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

Alcohol was added to a known amount of water-benzene mixture until one layer was obtained.

Source and Purity of Materials:
  1. Merck, "very pure," without acetone; used as received.
  2. Source not specified; used as received.
  3. Not specified.
Estimated Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.

Components:
  1. Methanol, $\ce{ CH4O }$; [67-56-1] NIST WebBook
  2. Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Compositions along the saturation curve
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
23.0296.2 0.25300.7240 0.42820.5026
26.0299.2 0.25200.7230 0.42490.5001
30.0303.2 0.25100.7200 0.41980.4939
19.0292.2 0.32250.6445 0.49960.4095
23.5296.7 0.32210.6444 0.49860.4092
24.0297.2 0.32170.6436 0.49690.4078
28.0301.2 0.32130.6428 0.49520.4064
31.0304.2 0.32090.6419 0.49340.4049
30.0303.2 0.32000.6410 0.49060.4031
25.5298.7 0.38200.5740 0.54910.3384
22.0295.2 0.38100.5730 0.54600.3368
30.0303.2 0.38100.5720 0.54490.3356
25.0298.2 0.46900.4700 0.60890.2503
29.0202.2 0.46800.4690 0.60590.2491
30.0303.2 0.46700.4680 0.60290.2478

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