Compilation - Ethanol with Benzene and Water (IUPAC SDS Volume 69)

SDS Volume (3870)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Staveley, L. A. K.; Johns, R. G. S.; Moore, B. C.; J. Chem. Soc. 1951, 2516-23.

Variables:

Room Temp: 274 - 342 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

The synthetic method was used. Mixtures were prepared in sealed tubes; water was added drom a weighted pipette to a known mass of alcohol-benzene mixture.

Source and Purity of Materials:
  1. Source not specified; dried by refluxing over freshly ignited lime, and then with magnesium, distilled.
  2. Source not specified; chemically purified, crystallized, distilled, dried over phosphoric anhydride.
  3. Source not specified.
Estimated Errors:

Ambient temperature: Composition <0.2%; temp. <0.2°C.
Mass concentration (m/v) (1): Not reported.

Components:
  1. Ethanol, $\ce{ C2H6O }$; [64-17-5] NIST WebBook
  2. Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Compositions along the saturation curve
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
27.2300.35 3.82 x 10-30.99546 6.44 x 10-30.99044
34.4307.55 3.82 x 10-30.99526 6.44 x 10-30.98960
42.2315.35 3.82 x 10-30.99495 6.44 x 10-30.98827
53.7326.85 3.83 x 10-30.99430 6.44 x 10-30.98554
55.2328.35 3.83 x 10-30.99419 6.44 x 10-30.98505
66.5339.65 3.84 x 10-30.99331 6.44 x 10-30.98137
14.7287.85 8.50 x 10-30.99104 0.01430.98369
32.6305.75 8.51 x 10-30.99054 0.01430.98160
37.4310.55 8.52 x 10-30.99031 0.01430.98068
46.4319.55 8.53 x 10-30.98984 0.01430.97873
51.6324.75 8.54 x 10-30.98952 0.01430.97738
68.7341.85 8.58 x 10-30.98807 0.01430.97142
26.1299.25 0.010900.98830 0.01830.97828
39.1312.25 0.010920.98778 0.01830.976145
45.4318.55 0.010930.98745 0.01830.97479
51.6324.75 0.010940.98712 0.01830.97343
60.6333.75 0.010970.98649 0.01830.97083
67.7340.85 0.010990.98595 0.01830.96864
18.7291.85 0.014730.98444 0.024650.97177
23.1296.25 0.014730.98429 0.024650.97116
26.6299.75 0.014740.98417 0.024650.97067
32.1305.25 0.014750.98395 0.024650.96978
41.6314.75 0.014770.98357 0.024650.96825
57.3330.45 0.014800.98295 0.024650.96576
61.7334.85 0.014820.98254 0.024650.96409
68.4341.55 0.014830.98217 0.024650.96260
16.7289.85 0.017890.98100 0.029860.96543
32.3305.45 0.017930.98043 0.029860.96313
43.4316.55 0.017950.98008 0.029860.96176
55.6328.75 0.017980.97954 0.029860.95961
11.5284.65 0.025400.97319 0.042130.95191
27.9301.05 0.025450.97260 0.042130.94960
38.6311.75 0.025480.97225 0.042130.94825
38.8311.95 0.025480.97223 0.042130.94817
39.0312.15 0.025480.97214 0.042130.94783
62.1335.25 0.025580.97095 0.042130.94325
1.3274.45 0.034150.96446 0.05630.93781
12.2285.35 0.034200.96396 0.05630.93595
27.5300.65 0.034260.96333 0.05630.93357
48.6321.75 0.034390.96208 0.05630.92893
13.0286.15 0.042250.95552 0.06910.92160
21.4294.55 0.042310.95502 0.06910.91978
32.6305.75 0.042400.95435 0.06910.91733
41.6314.75 0.042500.95351 0.06910.91430
56.5329.65 0.042600.95272 0.06910.91147

Download Data   link to XML output link to JSON output link to JSON-LD output