1-Octanol with Heptane and Water (IUPAC SDS Volume 69)

SDS Volume

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Source Publication

Kiryukhin, A. M.; Lesteva, T. M.; Markuzin, N. P.; Prom-st Sint. Kauch. 12, 12 (1981).

Conditions:

Room Temp: 293 - 333 $\pu{K}$

Compiler:

A. Skrzecz

Methodology:

After separation both phases were analyzed. Concentrations of organic components were determined by glc; water was determined by the Karl Fischer method. To determine hydrocarbon in the water-rich phase, samples were extracted by nonane.

Sample Information:
  1. Source not specified; distilled, dried over zeolite; purity >99.9% mass.
  2. Source not specified; distilled; purity >99.9 mass.
  3. Source not specified.
Measurement Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.

System Components:
  1. 1-Octanol, $\ce{ C8H18O }$; [111-87-5] NIST WebBook
  2. Heptane, $\ce{ C7H16 }$; [142-82-5] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
25293.2 0.00000.9999 0.00000.9994
25293.2 0.1710.826 0.1350.848
25293.2 0.3450.647 0.2770.676
25293.2 0.6470.330 0.5210.345
25293.2 0.7410.230 0.5930.239
25293.2 0.8630.100 0.6850.103
25293.2 0.9540.000 0.7420.000
25293.2 0.000003 x 10-6 0E-75 x 10-7
25293.2 7 x 10-52 x 10-6 9.7 x 10-64 x 10-7
25293.2 1.6 x 10-42 x 10-6 2.21 x 10-54 x 10-7
25293.2 3.1 x 10-41 x 10-6 4.29 x 10-52 x 10-7
25293.2 3.5 x 10-41 x 10-6 4.84 x 10-52 x 10-7
25293.2 3.8 x 10-40.000000 5.26 x 10-50E-7
25293.2 4.2 x 10-40.000000 5.81 x 10-50E-7
40313.2 0.00000.9999 0.00000.9994
40313.2 0.2570.739 0.2060.771
40313.2 0.4530.563 0.3690.567
40313.2 0.5970.382 0.4790.399
40313.2 0.6560.320 0.5270.334
40313.2 0.7680.206 0.6280.219
40313.2 0.8070.165 0.6590.175
40313.2 0.9000.064 0.7240.067
40313.2 0.9520.000 0.7330.000
40313.2 0.000006 x 10-6 0E-71.1 x 10-6
40313.2 1.0 x 10-45 x 10-6 1.38 x 10-59 x 10-7
40313.2 2.3 x 10-44 x 10-6 3.18 x 10-57 x 10-7
40313.2 2.5 x 10-43 x 10-6 3.46 x 10-55 x 10-7
40313.2 2.8 x 10-42 x 10-6 3.87 x 10-54 x 10-7
40313.2 2.9 x 10-41 x 10-6 4.01 x 10-52 x 10-7
40313.2 3.4 x 10-41 x 10-6 4.70 x 10-52 x 10-7
40313.2 4.0 x 10-40.000000 5.54 x 10-50E-7
40313.2 4.8 x 10-40.000000 6.64 x 10-50E-7
60333.2 0.00000.9998 0.00000.9989
60333.2 0.2000.799 0.1610.834
60333.2 0.4300.558 0.3460.584
60333.2 0.4860.498 0.3890.518
60333.2 0.5480.434 0.4410.454
60333.2 0.5910.388 0.4740.404
60333.2 0.6260.349 0.4970.360
60333.2 0.7370.233 0.5860.241
60333.2 0.8540.109 0.6760.112
60333.2 0.9490.000 0.7200.000
60333.2 0.000001.6 x 10-5 0E-72.9 x 10-6
60333.2 1.2 x 10-41.2 x 10-5 1.66 x 10-52.2 x 10-6
60333.2 2.0 x 10-41.0 x 10-5 2.77 x 10-51.8 x 10-6
60333.2 2.5 x 10-48 x 10-6 3.46 x 10-51.4 x 10-6
60333.2 2.8 x 10-45 x 10-6 3.87 x 10-59 x 10-7
60333.2 3.0 x 10-43 x 10-6 4.15 x 10-55 x 10-7
60333.2 3.2 x 10-42 x 10-6 4.43 x 10-54 x 10-7
60333.2 3.4 x 10-41 x 10-6 4.70 x 10-52 x 10-7
60333.2 3.9 x 10-40.000000 5.40 x 10-50E-7
60333.2 5.1 x 10-40.000000 7.06 x 10-50E-7

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