1-Octanol with Hexane (n-hexane) and Water (IUPAC SDS Volume 69)

SDS Volume

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Source Publication

Kiryukhin, A. M.; Lesteva, T. M.; Markuzin, N. P.; Prom-st Sint. Kauch. 12, 12 (1981).

Conditions:

Room Temp: 293 - 313 $\pu{K}$

Compiler:

A. Skrzecz

Methodology:

After separation both phases were analyzed. Concentration of organic components were determined by glc; water was determined by the Karl Fischer method. To determine hydrocarbon in the water-rich phase, samples were extracted by nonane.

Sample Information:
  1. Source not specified; distilled, dried over zeolite; purity >99.9% mass.
  2. Source not specified; distilled; purity >99.9% mass.
  3. Source not specified.
Measurement Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.

System Components:
  1. 1-Octanol, $\ce{ C8H18O }$; [111-87-5] NIST WebBook
  2. Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
25293.2 0.0000.999952 0.0000.999770
25293.2 0.2980.696 0.2140.755
25293.2 0.3630.629 0.2650.693
25293.2 0.4440.543 0.3270.604
25293.2 0.5210.462 0.3880.520
25293.2 0.5750.406 0.4340.463
25293.2 0.6080.373 0.4640.431
25293.2 0.6960.279 0.5360.325
25293.2 0.7710.199 0.5980.233
25293.2 0.8480.116 0.6610.137
25293.2 0.9540.000 0.7420.000
25293.2 0.000003.4 x 10-5 0E-77.1 x 10-6
25293.2 7 x 10-53.2 x 10-5 9.7 x 10-66.7 x 10-6
25293.2 1.3 x 10-43.0 x 10-5 1.80 x 10-56.3 x 10-6
25293.2 1.6 x 10-42.7 x 10-5 2.21 x 10-55.6 x 10-6
25293.2 1.9 x 10-42.4 x 10-5 2.63 x 10-55.0 x 10-6
25293.2 2.1 x 10-42.0 x 10-5 2.91 x 10-54.2 x 10-6
25293.2 2.3 x 10-41.5 x 10-5 3.18 x 10-53.1 x 10-6
25293.2 2.8 x 10-41.7 x 10-5 3.87 x 10-53.6 x 10-6
25293.2 3.0 x 10-41.0 x 10-5 4.15 x 10-52.1 x 10-6
25293.2 3.5 x 10-48 x 10-6 4.84 x 10-51.7 x 10-6
25293.2 4.2 x 10-40.000000 5.81 x 10-50E-7
40313.2 0.0000.9999 0.0000.9995
40313.2 0.000005.1 x 10-5 0E-71.07 x 10-5
40313.2 0.3740.616 0.2720.676
40313.2 1.2 x 10-43.7 x 10-5 1.66 x 10-57.7 x 10-6
40313.2 0.4820.503 0.3570.563
40313.2 2.1 x 10-42.8 x 10-5 2.91 x 10-55.9 x 10-6
40313.2 0.5260.458 0.3940.519
40313.2 2.2 x 10-42.5 x 10-5 3.04 x 10-55.2 x 10-6
40313.2 0.6080.373 0.4640.431
40313.2 2.7 x 10-42.0 x 10-5 3.74 x 10-54.2 x 10-6
40313.2 0.6240.352 0.4690.400
40313.2 2.8 x 10-41.8 x 10-5 3.87 x 10-53.8 x 10-6
40313.2 0.7030.273 0.5450.320
40313.2 3.0 x 10-41.5 x 10-5 4.15 x 10-53.1 x 10-6
40313.2 0.7400.234 0.5770.276
40313.2 3.2 x 10-41.0 x 10-5 4.43 x 10-52.1 x 10-6
40313.2 0.8660.096 0.6740.113
40313.2 4.0 x 10-44 x 10-6 5.54 x 10-58 x 10-7
40313.2 0.9520.000 0.7330.000
40313.2 4.8 x 10-40.000000 6.64 x 10-50E-7

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