SDS Volume
Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None
Source Publication
Washino, K.; Goto, S.; Matsubara, M.; Kagaku Kogaku 38, 869-73 (1974).
Conditions:
Room Temp: 363 $\pu{K}$
Compiler:
Methodology:
The cloud point method was used to find compositions along the saturation curve. The analytical method was used to describe phases in equilibrium. The ternary samples of about 50 mL were thermostated for 1 h, then the phases were separated and the compositions were determined by GLC analysis.
Sample Information:
- Source not specified, "high purity" commercial samples; used as received; purity > 99 mass% by glc.
- Source not specified, "high purity" commercial samples; used as received; purity > 99 mass% by glc.
- Distilled.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
System Components:
- Benzyl alcohol, $\ce{ C7H8O }$; [100-51-6] NIST WebBook
- 1,2,3,4-Tetrahydronaphthalene, $\ce{ C10H12 }$; [119-64-2] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | w1 | w2 | $x_{1}$ | $x_{2}$ |
|---|---|---|---|---|---|
| 90 | 363.2 | 0.2100 | 0.7840 | 0.2367 | 0.7227 |
| 90 | 363.2 | 0.4130 | 0.5760 | 0.4347 | 0.4958 |
| 90 | 363.2 | 0.5155 | 0.4645 | 0.5076 | 0.3741 |
| 90 | 363.2 | 0.5994 | 0.3720 | 0.5574 | 0.2830 |
| 90 | 363.2 | 0.6920 | 0.2760 | 0.6235 | 0.2034 |
| 90 | 363.2 | 0.7596 | 0.1769 | 0.5909 | 0.1126 |
| 90 | 363.2 | 0.8281 | 0.0857 | 0.5850 | 0.0495 |
| 90 | 363.2 | 0.8757 | 0.0000 | 0.5400 | 0.0000 |
