SDS Volume
Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None
Source Publication
Staveley, L. A. K.; Johns, R. G. S.; Moore, B. C.; J. Chem. Soc. 1951, 2516-23.
Conditions:
Room Temp: 284 - 341 $\pu{K}$
Compiler:
Methodology:
The synthetic method was used. Mixtures were prepared in a closed apparatus; components were degassed by repeated freezing, evacuation and melting; a known amount of each component was introduced into a tube by condensation and the tube was sealed. The volume of each tube was about 30 mL.
Sample Information:
- Source not specified; dried by refluxing over freshly-ignited lime, and then with aluminum amalgam, distilled.
- Source not specified; chemically purified, crystallized, distilled, dried over phosphoric anhydride.
- Source not specified.
Measurement Errors:
Ambient temperature: Composition <0.2%; temp. <0.2°C.
Mass concentration (m/v) (1): Not reported.
System Components:
- 1-Pentanol, $\ce{ C5H12O }$; [71-41-0] NIST WebBook
- Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ | w1 | w2 |
|---|---|---|---|---|---|
| 17.2 | 290.35 | 6.98 x 10-3 | 0.990830 | 7.886 x 10-3 | 0.991493 |
| 27.8 | 300.95 | 6.98 x 10-3 | 0.989217 | 7.893 x 10-3 | 0.991228 |
| 38.0 | 311.15 | 6.98 x 10-3 | 0.987591 | 7.903 x 10-3 | 0.990841 |
| 48.2 | 321.35 | 6.98 x 10-3 | 0.985602 | 7.915 x 10-3 | 0.990366 |
| 57.8 | 330.95 | 6.98 x 10-3 | 0.983010 | 7.931 x 10-3 | 0.989745 |
| 12.8 | 285.95 | 0.0119 | 0.985174 | 0.013439 | 0.985886 |
| 17.9 | 291.05 | 0.0119 | 0.984706 | 0.013443 | 0.985773 |
| 22.7 | 295.85 | 0.0119 | 0.984173 | 0.013449 | 0.985644 |
| 31.7 | 304.85 | 0.0119 | 0.983005 | 0.013461 | 0.985361 |
| 36.3 | 309.45 | 0.0119 | 0.982172 | 0.013470 | 0.985159 |
| 41.9 | 315.05 | 0.0119 | 0.981037 | 0.013482 | 0.984883 |
| 49.6 | 322.75 | 0.0119 | 0.979064 | 0.013502 | 0.984403 |
| 56.7 | 329.85 | 0.0119 | 0.977020 | 0.013524 | 0.983903 |
| 15.0 | 288.15 | 0.0223 | 0.973897 | 0.025167 | 0.973956 |
| 15.4 | 288.55 | 0.0223 | 0.973863 | 0.025167 | 0.973948 |
| 23.2 | 296.35 | 0.0223 | 0.972861 | 0.025187 | 0.973696 |
| 30.4 | 303.55 | 0.0223 | 0.971906 | 0.025205 | 0.973456 |
| 37.6 | 310.75 | 0.0223 | 0.970902 | 0.025225 | 0.973204 |
| 37.9 | 311.05 | 0.0223 | 0.970753 | 0.025228 | 0.973166 |
| 47.3 | 320.45 | 0.0223 | 0.968898 | 0.025264 | 0.972698 |
| 58.3 | 331.45 | 0.0223 | 0.966120 | 0.025318 | 0.971995 |
| 16.7 | 289.85 | 0.0281 | 0.966134 | 0.031737 | 0.966933 |
| 17.4 | 290.55 | 0.0281 | 0.966047 | 0.031739 | 0.966910 |
| 29.0 | 302.15 | 0.0281 | 0.064932 | 0.031766 | 0.966624 |
| 37.4 | 310.55 | 0.0281 | 0.964059 | 0.031787 | 0.966400 |
| 45.0 | 318.15 | 0.0281 | 0.963049 | 0.031812 | 0.966140 |
| 51.8 | 324.95 | 0.0281 | 0.962049 | 0.031837 | 0.965882 |
| 18.1 | 291.25 | 0.0486 | 0.943586 | 0.054831 | 0.943367 |
| 31.2 | 304.35 | 0.0486 | 0.941986 | 0.054899 | 0.942928 |
| 43.1 | 316.25 | 0.0486 | 0.940190 | 0.054975 | 0.942433 |
| 52.0 | 325.15 | 0.0486 | 0.938650 | 0.055040 | 0.942009 |
| 68.0 | 341.15 | 0.0486 | 0.936460 | 0.055134 | 0.941403 |
| 11.2 | 284.35 | 0.08425 | 0.904960 | 0.094835 | 0.902683 |
| 28.4 | 301.55 | 0.08425 | 0.902230 | 0.095034 | 0.901849 |
| 43.3 | 316.45 | 0.08425 | 0.899660 | 0.095223 | 0.901061 |
| 57.8 | 330.95 | 0.08425 | 0.896850 | 0.095429 | 0.900196 |
