SDS Volume
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 152
Source Publication
Parsons, G. H.; Rochester, C. H.; Wood, C. E. C.; J. Chem. Soc. B 1971, 533-6.
Conditions:
Room Temp: 25 °C
Compiler:
Methodology:
The experimental prcedure was probably similar to that reported in [1]. Excess solid was shaken with water at 25 ± 0.1 °C for 24 hours. The saturated solution was then filtered at thermostat temperature and, with appropriate dilution, analyzed spectrophotometically. Linear calibration graphs of absorbance at a wave length of maximum absorbance of the neutral phenols against concentration confirmed the applicability of the Beer-Lambert law for the analysis.
Sample Information:
- Commercial product (manufacturer not reported), recrystallized to a constant melting point.
- Source and purity not specified.
Measurement Errors:
Mass concentration (m/v) (1): ±2% (standard deviation of the average value from five determinations as reported by the authors).
Methodology Citation
System Components:
- 4-Bromophenol, $\ce{ C6H5BrO }$; [106-41-2] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | MR1 (g/kg) | m1 (mol/kg) |
|---|---|---|---|
| 25 | 1.9330 x 10-3a | 18.261a | 0.1075b |
(a) Calculated by F. W. Getzen.
(b) Reported.


