SDS Volume
Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None
Source Publication
Shanahan, C. E. A.; Analyst 73, 502 (1948).
Conditions:
Room Temp: 293 $\pu{K}$
Compiler:
Methodology:
The titration method was used. Binary toluene-butanol mixtures (100 g) of known compositions in 300 mL glass stoppered bottles were titrated with distilled water until a second phase appeared and persisted on prolonged vigorous shaking.
Sample Information:
- Source not specified.
- Source not specified.
- Source not specified.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
System Components:
- 1-Butanol, $\ce{ C4H10O }$; [71-36-3] NIST WebBook
- Toluene, $\ce{ C7H8 }$; [108-88-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | w1 | w2 | $x_{1}$ | $x_{2}$ |
|---|---|---|---|---|---|
| 20 | 293.15 | 0.8013 | 0.0000 | 0.4950 | 0.0000 |
| 20 | 293.15 | 0.6667 | 0.2367 | 0.5314 | 0.1518 |
| 20 | 293.15 | 0.4625 | 0.4931 | 0.4439 | 0.3807 |
| 20 | 293.15 | 0.2344 | 0.7506 | 0.2605 | 0.6710 |
| 20 | 293.15 | 0.0 | 0.9990 | 0.0000 | 0.9949 |
