SDS Volume
Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None
Source Publication
Staveley, L. A. K.; Johns, R. G. S.; Moore, B. C.; J. Chem. Soc. 1951, 2516-23.
Conditions:
Room Temp: 286 - 333 $\pu{K}$
Compiler:
Methodology:
The synthetic method was used. Mixtures were prepared in a closed apparatus; components were degassed by repeated freezing, evacuation, and melting; a known amount of each component was introduced into a tube by condensation and the tube was sealed. The volume of each tube was about 30 mL.
Sample Information:
- Source not specified; dried by refluxing over freshly ignited lime, and then with aluminum amalgam, distilled. Source not specified; used as received.
- Source not specified; chemically purified, crystallized, distilled, dried over phosphoric anhydrous.
- Source not specified.
Measurement Errors:
Ambient temperature: Composition <0.2%; temp. <0.2°C.
Mass concentration (m/v) (1): Not reported.
System Components:
- 1-Butanol, $\ce{ C4H10O }$; [71-36-3] NIST WebBook
- Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ | w1 | w2 |
|---|---|---|---|---|---|
| 24.7 | 297.85 | 8.02 x 10-3 | 0.988708 | 7.633 x 10-3 | 0.991611 |
| 32.6 | 305.75 | 8.02 x 10-3 | 0.987635 | 7.639 x 10-3 | 0.991355 |
| 42.3 | 315.45 | 8.02 x 10-3 | 0.985953 | 7.649 x 10-3 | 0.990954 |
| 51.5 | 324.65 | 8.02 x 10-3 | 0.983756 | 7.662 x 10-3 | 0.990429 |
| 16.8 | 289.95 | 0.01405 | 0.982584 | 0.013376 | 0.985845 |
| 35.6 | 308.75 | 0.01405 | 0.979741 | 0.013406 | 0.985154 |
| 45.1 | 318.25 | 0.01405 | 0.977894 | 0.013425 | 0.984704 |
| 54.2 | 327.35 | 0.01405 | 0.975570 | 0.013449 | 0.984136 |
| 18.8 | 291.95 | 0.02615 | 0.969185 | 0.024937 | 0.973982 |
| 26.8 | 299.95 | 0.02615 | 0.968104 | 0.024958 | 0.973709 |
| 35.0 | 308.15 | 0.02615 | 0.966882 | 0.024981 | 0.973401 |
| 44.0 | 317.15 | 0.02615 | 0.965339 | 0.025011 | 0.973010 |
| 51.9 | 325.05 | 0.02615 | 0.963580 | 0.025045 | 0.972564 |
| 14.8 | 287.95 | 0.0329 | 0.961345 | 0.031411 | 0.967254 |
| 26.4 | 299.55 | 0.0329 | 0.960018 | 0.031443 | 0.966912 |
| 34.3 | 307.45 | 0.0329 | 0.959035 | 0.031467 | 0.966658 |
| 45.9 | 319.05 | 0.0329 | 0.957355 | 0.031508 | 0.966223 |
| 57.9 | 331.05 | 0.0329 | 0.955300 | 0.031559 | 0.965690 |
| 12.6 | 285.75 | 0.0561 | 0.935951 | 0.053716 | 0.944434 |
| 24.1 | 297.25 | 0.0561 | 0.934520 | 0.053776 | 0.944039 |
| 35.9 | 309.05 | 0.0561 | 0.93289 | 0.053844 | 0.943587 |
| 47.2 | 320.35 | 0.0561 | 0.93123 | 0.053914 | 0.943127 |
| 60.2 | 333.35 | 0.0561 | 0.92923 | 0.053998 | 0.942570 |
| 13.8 | 286.95 | 0.0973 | 0.89040 | 0.093681 | 0.903441 |
| 24.3 | 297.45 | 0.0973 | 0.88851 | 0.093820 | 0.902855 |
| 35.6 | 308.75 | 0.0973 | 0.88645 | 0.093971 | 0.902215 |
| 46.8 | 319.95 | 0.0973 | 0.88433 | 0.094127 | 0.901554 |
| 59.5 | 332.65 | 0.0973 | 0.88173 | 0.094320 | 0.900740 |
