SDS Volume
Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None
Source Publication
Letcher, T. M.; Siswana, P. M.; van der Watt, P.; Radloff, S.; J. Chem. Thermodyn. 21, 1053 (1989).
Conditions:
Room Temp: 298 $\pu{K}$
Compiler:
Methodology:
The titration method was used to determine binodal curve. A binary mixture of known composition was titrated with the third component until cloudiness was observed. Tie line compositions were related to the coexistence curve; water was determined by the Karl Fischer titration. The methods were described in [1].
Sample Information:
- Source not specified; used as received.
- Source not specified; recrystallized three times.
- Source not specified.
Measurement Errors:
Ambient temperature: Comp. <0.005 mole fraction (estimated authors' precision on binodal curve), <0.01 mole fraction (estimated authors' precision of tie lines).
Mass concentration (m/v) (1): Not reported.
Methodology Citation
1 Letcher, T. M.; Wootton, S.; Shuttleworth, B.; Heyward, C.; J. Chem. Thermodyn 18, 1037 (1986).
System Components:
- 2-Methyl-1-propanol, $\ce{ C4H10O }$; [78-83-1] NIST WebBook
- 1,4-Dimethylbenzene, $\ce{ C8H10 }$; [106-42-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | $x_{2}$ | w1 | w2 |
|---|---|---|---|---|---|
| 25.0 | 298.2 | 0.000 | 0.998 | 0.0 | 0.9997 |
| 25.0 | 298.2 | 0.069 | 0.916 | 0.050 | 0.948 |
| 25.0 | 298.2 | 0.135 | 0.843 | 0.100 | 0.896 |
| 25.0 | 298.2 | 0.249 | 0.695 | 0.198 | 0.791 |
| 25.0 | 298.2 | 0.345 | 0.561 | 0.295 | 0.686 |
| 25.0 | 298.2 | 0.422 | 0.444 | 0.387 | 0.583 |
| 25.0 | 298.2 | 0.530 | 0.247 | 0.565 | 0.377 |
| 25.0 | 298.2 | 0.558 | 0.167 | 0.646 | 0.277 |
| 25.0 | 298.2 | 0.571 | 0.105 | 0.714 | 0.188 |
| 25.0 | 298.2 | 0.572 | 0.011 | 0.830 | 0.023 |
| 25.0 | 298.2 | 0.548 | 0.000 | 0.833 | 0.000 |
| 25.0 | 298.2 | 0.021 | 0.000 | 0.081 | 0.000 |
