SDS Volume (3696)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Vorobeva, A. I.; Karapetyants, M. Kh.; Zh. Fiz. Khim. 41, 1144 (1967).

Variables:

Room Temp: 298 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

The methods were reported in [1]. The titration method was used to describe solubility of the mixtures. The third component was added to the binary homogeneous mixture until the cloudiness started to be observed. Density of the saturated mixtures was measured and put on the graphs. To obtain equilibrium ternary mixtures were stirred in thermostated vessel through several hours. After phase separation, density of each phase prepared graphs. Concentration at critical point was found by the method described in [2]. Water include in propanol was taken into account in all measurements.

Source and Purity of Materials:
  1. Source not specified, chemical pure grade; distilled; water concentrations was determined by the Karl Fischer method.
  2. Source not specified; properties were the same as reported in [1].
  3. Doubly distilled.
Estimated Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.

References

1 Vorobeva, A. I.; Karapetyants, M. Kh.; Zh. Fiz. Khim. 40, 3018 (1966).
2 Zilberman,E. N.; Zh. Fiz. Khim. 26, 1458 (1952).

Components:
  1. 1-Propanol, $\ce{ C3H8O }$; [71-23-8] NIST WebBook
  2. Heptane, $\ce{ C7H16 }$; [142-82-5] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Compositions along the saturation curve
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
25298.2 0.0000.999 0.00000.9945
25298.2 0.0540.944 0.08610.9032
25298.2 0.1250.867 0.18610.7742
25298.2 0.1590.828 0.22750.7105
25298.2 0.2190.758 0.29190.6059
25298.2 0.2700.696 0.33710.5212
25298.2 0.4050.521 0.42000.3240
25298.2 0.4820.414 0.44740.2305
25298.2 0.5460.316 0.45660.1585
25298.2 0.5920.206 0.42610.0889
25298.2 0.5890.134 0.36970.0504
25298.2 0.5600.091 0.31480.0307
25298.2 0.5060.054 0.25220.0161
25298.2 0.4070.023 0.17535.9 x 10-3
25298.2 0.2847 x 10-3 0.10701.6 x 10-3
25298.2 0.1673 x 10-3 0.05696 x 10-4

(a) Critical solubility point.

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