SDS Volume

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Source Publication

Nikurashina, N. I.; Ilin, K. K.; Zh. Obshch. Khim. 42, 1657 (1972).

Conditions:

Room Temp: 298 $\pu{K}$

Compiler:

A. Skrzecz

Methodology:

The isothermal titration method was used. Phase equilibrium was determined by the secants method. Each secant represented a constant water-toluene mass ratio, the concentration of 1-propanol was variable. After 24 h separation, refractive indexes of both phases were measured. Equilibrium concentration of 1-propanol in both phases, in weight percent, was reported for 15 tie lines.

Sample Information:
  1. Source not specified, chemically pure grade: used as received; BP = 97.4°C, $n_{D}^{20}$ = 1.3858.
  2. Source not specified, pure for analysis grade; used as received; BP = 110.6°C, $n_{D}^{20}$ = 1.4967.
  3. Freshly distilled water, $n_{D}^{20}$ = 1.3332.
Measurement Errors:

Ambient temperature: Temp. ±0.1°C.
Mass concentration (m/v) (1): Not reported.

Methodology Citation

1 Nikurashina, N. I.; Mertslin, R. V.; Method of Secants (in Russian), Saratov University, 1969.

System Components:
  1. 1-Propanol, $\ce{ C3H8O }$; [71-23-8] NIST WebBook
  2. Toluene, $\ce{ C7H8 }$; [108-88-3] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
25.0298.2 0.19962.2 x 10-3 0.06975 x 10-4
25.0298.2 0.29530.0155 0.11343.9 x 10-3
25.0298.2 0.37310.0376 0.15790.0104
25.0298.2 0.38410.0398 0.16470.0111
25.0298.2 0.40420.0467 0.17830.0134
25.0298.2 0.41300.0495 0.18450.0144
25.0298.2 0.42160.0525 0.19080.0155
25.0298.2 0.43270.0567 0.19910.0170
25.0298.2 0.46540.0692 0.22560.0219
25.0298.2 0.51800.0964 0.27740.0337
25.0298.2 0.55290.1342 0.32830.0520
25.0298.2 0.57000.1720 0.36950.0727
25.0298.2 0.56660.2167 0.39600.0988
25.0298.2 0.55810.2651 0.42260.1309
25.0298.2 0.52840.3301 0.43460.1771
25.0298.2 0.48420.4126 0.44120.2452
25.0298.2 0.38430.5530 0.40280.3780
25.0298.2 0.28960.6757 0.34230.5209
25.0298.2 0.19660.7861 0.25630.6684
25.0298.2 0.09940.8952 0.14170.8326

(a) The same concentration of 1-propanol in both phases.

Download Data   link to XML output link to JSON output link to JSON-LD output