SDS Volume
Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None
Source Publication
Nikurashina, N. I.; Ilin, K. K.; Zh. Obshch. Khim. 42, 1657 (1972).
Conditions:
Room Temp: 298 $\pu{K}$
Compiler:
Methodology:
The isothermal titration method was used. Phase equilibrium was determined by the secants method. Each secant represented a constant water-toluene mass ratio, the concentration of 1-propanol was variable. After 24 h separation, refractive indexes of both phases were measured. Equilibrium concentration of 1-propanol in both phases, in weight percent, was reported for 15 tie lines.
Sample Information:
- Source not specified, chemically pure grade: used as received; BP = 97.4°C, $n_{D}^{20}$ = 1.3858.
- Source not specified, pure for analysis grade; used as received; BP = 110.6°C, $n_{D}^{20}$ = 1.4967.
- Freshly distilled water, $n_{D}^{20}$ = 1.3332.
Measurement Errors:
Ambient temperature: Temp. ±0.1°C.
Mass concentration (m/v) (1): Not reported.
Methodology Citation
1 Nikurashina, N. I.; Mertslin, R. V.; Method of Secants (in Russian), Saratov University, 1969.
System Components:
- 1-Propanol, $\ce{ C3H8O }$; [71-23-8] NIST WebBook
- Toluene, $\ce{ C7H8 }$; [108-88-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | w1 | w2 | $x_{1}$ | $x_{2}$ |
|---|---|---|---|---|---|
| 25.0 | 298.2 | 0.1996 | 2.2 x 10-3 | 0.0697 | 5 x 10-4 |
| 25.0 | 298.2 | 0.2953 | 0.0155 | 0.1134 | 3.9 x 10-3 |
| 25.0 | 298.2 | 0.3731 | 0.0376 | 0.1579 | 0.0104 |
| 25.0 | 298.2 | 0.3841 | 0.0398 | 0.1647 | 0.0111 |
| 25.0 | 298.2 | 0.4042 | 0.0467 | 0.1783 | 0.0134 |
| 25.0 | 298.2 | 0.4130 | 0.0495 | 0.1845 | 0.0144 |
| 25.0 | 298.2 | 0.4216 | 0.0525 | 0.1908 | 0.0155 |
| 25.0 | 298.2 | 0.4327 | 0.0567 | 0.1991 | 0.0170 |
| 25.0 | 298.2 | 0.4654 | 0.0692 | 0.2256 | 0.0219 |
| 25.0 | 298.2 | 0.5180 | 0.0964 | 0.2774 | 0.0337 |
| 25.0 | 298.2 | 0.5529 | 0.1342 | 0.3283 | 0.0520 |
| 25.0 | 298.2 | 0.5700 | 0.1720 | 0.3695 | 0.0727 |
| 25.0 | 298.2 | 0.5666 | 0.2167 | 0.3960 | 0.0988 |
| 25.0 | 298.2 | 0.5581 | 0.2651 | 0.4226 | 0.1309 |
| 25.0 | 298.2 | 0.5284 | 0.3301 | 0.4346 | 0.1771 |
| 25.0 | 298.2 | 0.4842 | 0.4126 | 0.4412 | 0.2452 |
| 25.0 | 298.2 | 0.3843 | 0.5530 | 0.4028 | 0.3780 |
| 25.0 | 298.2 | 0.2896 | 0.6757 | 0.3423 | 0.5209 |
| 25.0 | 298.2 | 0.1966 | 0.7861 | 0.2563 | 0.6684 |
| 25.0 | 298.2 | 0.0994 | 0.8952 | 0.1417 | 0.8326 |
(a) The same concentration of 1-propanol in both phases.


