SDS Volume

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Source Publication

Washburn, E. R.; Brockway, C. E.; Graham, C. L.; Deming, P.; J. Am. Chem. Soc. 64, 1886 (1942).

Conditions:

Room Temp: 298 - 308 $\pu{K}$

Compiler:

A. Skrzecz

Methodology:

The titration method [1,2], was used. Binary mixtures of known composition were titrated with the third component. The total weight of liquids employed was 13-15 g. The refractive indexes of mixtures were used to construct the refractive index/composition curve, which was used further to find compositions of equilibrium phases.

Sample Information:

1. Eastman Kodak Company, best grade; dried with active lime, distilled; $d_{4}^{25}$ = 0.8000, $n_{D}^{25}$ = 1.3838.
2. Eastman Kodak Company; distilled, dried with $\ce{Na}$, recrystallized several times; $d_{4}^{25}$ = 0.7746, $n_{D}^{25}$ = 1.4232, FP = 6.1°C.
3. Source not specified.

Measurement Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.

Methodology Citations

¹ Vold, R. D.; Washburn, E. R.; J. Am. Chem. Soc. 54, 4217 (1932).
² Washburn, E. R.; Spencer, H. C.; J. Am. Chem. Soc. 56, 361-4 (1934).