SDS Volume
Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None
Source Publication
Bonner, W. D.; J. Phys. Chem. 14, 738 (1909).
Conditions:
Room Temp: 273 $\pu{K}$
Compiler:
Methodology:
In a tube 1 cm diameter and 12 cm long known amount, by weight, of hydrocarbon and water were placed into a temperature controlled bath. The contents of the tube were stirred and alcohol was added gradually until a homogeneous solution was obtained. Observations were made visually through the telescope of a cathetometer. The samples were always weighed immediately before and after each experiment. Concentrations were reported as weight of water in 1 g of binary water-hydrocarbon mixture and the weight of alcohol necessary to make a homogenous solution. The mass of binary water-hydrocarbon mixture was about 1 g; the mass of alcohol-up to 5 g.
Sample Information:
- Kahlbaum; presumably dried and distilled.
- Kahlbaum; presumably dried and distilled.
- Source not specified.
Measurement Errors:
Ambient temperature: Accuracy of weighing 0.0001 g.
Mass concentration (m/v) (1): Not reported.
System Components:
- Ethanol, $\ce{ C2H6O }$; [64-17-5] NIST WebBook
- 1,3,5-Trimethylbenzene, $\ce{ C9H12 }$; [108-67-8] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | w1 | w2 | $x_{1}$ | $x_{2}$ |
|---|---|---|---|---|---|
| 0.0 | 273.2 | 0.3243 | 0.6554 | 0.5170 | 0.4004 |
| 0.0 | 273.2 | 0.3404 | 0.6352 | 0.5267 | 0.3767 |
| 0.0 | 273.2 | 0.4952 | 0.4594 | 0.6289 | 0.2236 |
| 0.0 | 273.2 | 0.5956 | 0.3381 | 0.6657 | 0.1448 |
| 0.0 | 273.2 | 0.6700 | 0.2317 | 0.6632 | 0.0879 |
| 0.0 | 273.2 | 0.7028 | 0.1697 | 0.6425 | 0.0595 |
| 0.0 | 273.2 | 0.7275 | 0.0779 | 0.5797 | 0.0238 |
| 0.0 | 273.2 | 0.7135 | 0.0570 | 0.5396 | 0.0165 |
| 0.0 | 273.2 | 0.6992 | 0.0331 | 0.5007 | 9.1 x 10-3 |
| 0.0 | 273.2 | 0.6176 | 0.0195 | 0.3977 | 4.8 x 10-3 |


