SDS Volume
Volume 37. Hydrocarbons in Water and Seawater, Part I, p 28
Source Publication
McAuliffe, C.; J. Phys. Chem. 1966, 70, 1267-1275.
Conditions:
Room Temp: 25 °C
Compilers:
Z. Maczynska, A. Maczynski, A. Szafranski
Methodology:
In a 250 mL glass bottle, 10-20 mL of (1) was vigorously shaken for 1 hr or magnetically stirred for one day, with 200 mL of (2) at 25 °C. In the case of shaking, the solution was allowed to stand for two days to permit separation of small (1) droplets. Absence of emulsion was checked microscopically. A sample of the hydrocarbon-saturated water was withdrawn with a Hamilton syringe and gas liquid chromatographed in conjunction with a flame-ionization detector.
Sample Information:
- Phillips Petroleum or Columbia Chemical; used as received.
- Distilled.
Measurement Errors:
Ambient temperature: ±1.5 K
Mass concentration (m/v) (1): 7 g(1)/106 g(2) (standard deviation of mean)
System Components:
- 1-Pentene, $\ce{ C5H10 }$; [109-67-1] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
The solubility of 1-pentene in water at 25°C was reported to be 148 g(1)/106 g(2).
The corresponding mass percent and mole fraction, x1, calculated by the compilers are 0.0148 g(1)/100 g sln and 3.80 × 10-5.
