Compilation - Ethanol with o-Xylene and Water (IUPAC SDS Volume 69)

SDS Volume (3652)

Volume 69. Ternary Alcohol-Hydrocarbon-Water Systems, p None

Original Measurements

Bonner, W. D.; J. Phys. Chem. 14, 738 (1909).

Variables:

Room Temp: 273 $\pu{K}$

Prepared by:

A. Skrzecz

Method/Apparatus/Procedure:

In a tube 1 cm diameter and 12 cm long known amount, by weight, of hydrocarbon and water were placed into a temperature controlled bath. The contents of the tube were stirred and alcohol was added gradually until a homogeneous solution was obtained. Observations were made visually through the telescope of a cathetometer. The samples were always weighed immediately before and after each experiment. Concentrations were reported as weight of water in 1 g of binary water-hydrocarbon mixture and the weight of alcohol necessary to make a homogenous solution. The mass of binary water-hydrocarbon mixture was about 1 g; the mass of alcohol-up to 5 g.

Source and Purity of Materials:
  1. Kahlbaum; presumably dried and distilled.
  2. Kahlbaum; presumably dried and distilled.
  3. Source not specified.
Components:
  1. Ethanol, $\ce{ C2H6O }$; [64-17-5] NIST WebBook
  2. 1,2-Dimethylbenzene, $\ce{ C8H10 }$; [95-47-6] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Compositions along the saturation curve
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
0.0273.2 0.26040.71820.41530.4972
0.0273.2 0.34640.62750.50530.3972
0.0273.2 0.51810.41980.60300.2120
0.0273.2 0.56900.33880.59770.1544
0.0273.2 0.60940.26870.58730.1124
0.0273.2 0.64850.18140.55800.0677
0.0273.2 0.66160.12590.52520.0434
0.0273.2 0.64450.07390.46150.0230
0.0273.2 0.62120.03790.41160.0109
0.0273.2 0.54340.01420.32323.7 x 10-3

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