SDS Volume
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Source Publication
Antropov, L. I.; Populyai, V. E.; Simonov, V. D.; Shamsutdinov, T. M.; Russ. J. Phys. Chem. 1972, 46, 311-2.
Conditions:
Room Temp: 288 - 299 $\pu{K}$
Compiler:
Methodology:
The Alexejew's synthetic method of solubility determination was used [1]. A fixed weight of water and 1,1,2,3,3,3-hexachloro-1-propene was sealed in a tube and subjected to gradually increasing temperature with constant agitation. The appearance of an opalescence or clouding was an indication of saturation temperature. The temperature was then allowed to fall and an observation made, while the tube was constantly agitated, to establish the temperature of the first appearance of opalescence. The observation was repeated several times.
Sample Information:
- Synthesized by the investigators, purified by fractional distillation and dried with $\ce{CaCl2}$ and $\ce{P2O5}$.
- Distilled.
Measurement Errors:
Ambient temperature: ±1 K (compiler).
Mass concentration (m/v) (1): Not specified.
Methodology Citation
System Components:
- 1,1,2,3,3,3-Hexachloro-1-propene, $\ce{ C3Cl6 }$; [1888-71-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | w1 | w2 | $x_{1}$ | $x_{2}$ |
|---|---|---|---|---|
| 15 | 9.47 x 10-4 | - | 6.86 x 10-7 | - |
| 18 | - | 3.71 x 10-3 | - | 5.12 x 10-4 |
| 20 | 1.18 x 10-3 | - | 8.55 x 10-7 | - |
| 22 | - | 4.38 x 10-3 | - | 6.04 x 10-4 |
| 26 | 1.70 x 10-3 | 5.25 x 10-3 | 1.231 x 10-6 | 7.24 x 10-4 |
