Compilation - 1,3-Dichloropropane with Water (IUPAC SDS Volume 68)
SDS Volume (3614)
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Original Measurements
Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.
Variables:
Room Temp: 275 - 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A 5 μL 1,3-dichloropropane sample was in-jected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,3-dichloropropane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Source and Purity of Materials:
- Source and purity not given.
- distilled.
Estimated Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±5.0%.
Components:
- 1,3-Dichloropropane, $\ce{ C3H6Cl2 }$; [142-28-9] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | DL |
|---|---|---|---|
| 1.9 | 0.2101 | 3.356 x 10-4 | 17.71 |
| 13.5 | 0.2434 | 3.889 x 10-4 | 31.70 |
| 15.7 | 0.2395 | 3.837 x 10-4 | 36.21 |
| 17.1 | 0.2558 | 4.087 x 10-4 | 37.14 |
| 22 | 0.2814 | 4.497 x 10-4 | 44.97 |
| 24.9 | 0.2789 | 4.458 x 10-4 | 53.57 |
(a) Gas-liquid system analysis parameter, from calibration measurements.
