SDS Volume (3575)

Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None

Original Measurements

Tewari, Y. B.; Miller, M. M.; Wasik, S. P.; Martire, D. E.; J. Chem. Eng. Data 1982, 27, 451-4.

Variables:

Room Temp: 298 $\pu{K}$

Prepared by:

A.L. Horvath

Method/Apparatus/Procedure:

The modified generator column method was used. A chromatographic column was coated with liquid 1-bromo-3-chloropropane. An aqueous phase was generated by pumping water through the coated generator column. The aqueous solution was analyzed by a gas chromatographic method using a gas chromatograph equipped with a flame ionization detector.

Source and Purity of Materials:
  1. Source not given. At least 99% pure by GC analysis.
  2. Baker-analyzed HPLC grade.
Estimated Errors:

Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±1.0%.

Components:
  1. 1-Bromo-3-chloropropane, $\ce{ C3H6BrCl }$; [109-70-6] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $C_{1}$ (mol/dm3) 100w1 $x_{1}$
25 0.0142 0.2232.56 x 10-4

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